Phosphorus pentasulfide mediated conversion of organic thiocyanates to thiols

Scholarly Works

• Dr. Nagesh Raghunath Sutar. A Simplified Approach to α-Ketothiocyanates, Thiocyanatoindoles and Chalcones Using Lithium Chloride. International Journal of Scientific Research in Chemistry 2025, 10, 1–14. doi:10.32628/ijsrch251051
• Kerr, T. A.; Nelson, Y. A.; Bernier, N. A.; Spokoyny, A. M. An Electrochemical Strategy for Chalcogenation of closo-Dodecaborate (B12H12)2- Anion. Inorganic chemistry 2025, 64, 8845–8850. doi:10.1021/acs.inorgchem.5c00469
• Magné, V.; Serusi, L.; Gulea, M.; Hanquet, G.; Madec, D.; Panossian, A. Reduction of S O and SO2 to S, S–X to S–H, and P O to P. Comprehensive Organic Synthesis; Elsevier, 2025; pp 108–164. doi:10.1016/b978-0-323-96025-0.00122-8
• Gupta, M.; Charpe, V. P.; Hwang, K. C. Singlet Oxygen-Mediated Regioselective Thiocyanation of Terminal Alkynes, Alkenes, Indoles, Pyrrole, Anilines, and Phenols. ACS Sustainable Chemistry & Engineering 2024, 12, 16297–16307. doi:10.1021/acssuschemeng.4c05654
• Hao, J.; Lv, Y.; Tian, S.; Ma, C.; Cui, W.; Yue, H.; Wei, W.; Yi, D. Additive-free synthesis of β-keto phosphorodithioates via geminal hydro-phosphorodithiolation of sulfoxonium ylides with P4S10 and alcohols. Chinese Chemical Letters 2024, 35, 109513. doi:10.1016/j.cclet.2024.109513
• Saha, S.; Pinheiro, A. B.; Chatterjee, A.; Bhutia, Z. T.; Banerjee, M. A solvent-free mechanochemical electrophilic C–H thiocyanation of indoles and imidazo[1,2-a]pyridines using a cost-effective combination of N-chlorosuccinimide-NaSCN and tandem C–C and C–S bond formation. Green Chemistry 2024, 26, 5879–5889. doi:10.1039/d4gc00486h
• Qumruddeen; Kumar, D.; Jose, J.; Tripathi, C. B. Lewis Base Catalyzed C−S Bond Formation Through Methyl C(sp3)‐H Thiocyanation of Indoles. Asian Journal of Organic Chemistry 2024, 13. doi:10.1002/ajoc.202300495
• Buttard, F.; Vigier, J.; Lebel, H.; Besset, T. C‐Centered radical intermediates for C(sp3)‐H bonds functionalization: An emerging approach towards alkyl thiocyanates. European Journal of Organic Chemistry 2024, 27. doi:10.1002/ejoc.202301205
• Qu, C.; Wang, Y.; Lv, Y.; Yue, H.; Wei, W.; Yi, D. Metal-free hydrophosphorodithiolation of alkynes with P4S10 and alcohols leading to vinyl phosphorodithioates. Organic Chemistry Frontiers 2023, 11, 171–175. doi:10.1039/d3qo01588b
• Qu, C.; Lv, Y.; Huang, J.; Ma, C.; Yue, H.; Wei, W.; Yi, D. Additive-free aerobic oxidative difunctionalization of alkenes with P4S10 and alcohols to access β-hydroxy phosphorodithioates. Green Chemistry 2023, 25, 10678–10683. doi:10.1039/d3gc02665e
• Sharma, A.; Gola, A. K.; Pandey, S. K. Straightforward access to α-thiocyanoketones and thiazoles from sulfoxonium ylides. Chemical communications (Cambridge, England) 2023, 59, 10247–10250. doi:10.1039/d3cc02401f
• Xia, W.; Hu, L.; Ma, C.; Cao, J.; Zhang, X.; Xiong, Y. Thiocyanation of Allylic Alcohols Promoted by Trifluoroacetic Acid. European Journal of Organic Chemistry 2023, 26. doi:10.1002/ejoc.202300148
• Chen, S.; Yan, Q.; Fan, J.; Guo, C.; Li, L.; Liu, Z.-Q.; Li, Z. Photo-induced spirocyclization of biaryl ynones with ammonium thiocyanate: access to thiocyanate-featured spiro[5,5]trienones. Green Chemistry 2023, 25, 153–160. doi:10.1039/d2gc03710f
• Maeda, B.; Aihara, Y.; Sato, A.; Kinoshita, T.; Murakami, K. Photoinduced Synthesis of Thiocyanates through Hydrogen Atom Transfer and One-Pot Derivatization to Isothiocyanates. Organic letters 2022, 24, 7366–7371. doi:10.1021/acs.orglett.2c02896
• Chen, S.; Yan, Q.; Fan, J.; Gao, Y.; Yang, X.; Li, L.; Liu, Z.; Li, Z. Photoinduced cascade cyclization of alkynes with NH4SCN: access to SCN-containing dibenzazepines or dioxodibenzothiazepines. Green Chemistry 2022, 24, 4742–4747. doi:10.1039/d2gc01276f
• Duan, Y.; Liang, K.; Yin, H.; Chen, F. Dithiocyanation of Alkynes with N‐Thiocyanato‐dibenzenesulfonimide and Ammonium Thiocyanate. European Journal of Organic Chemistry 2022, 2022. doi:10.1002/ejoc.202200359
• Lyalin, B. V.; Sigacheva, V. L.; Kudinova, A. S.; Neverov, S. V.; Kokorekin, V. A.; Petrosyan, V. A. Electrooxidation Is a Promising Approach to Functionalization of Pyrazole-Type Compounds. Molecules (Basel, Switzerland) 2021, 26, 4749. doi:10.3390/molecules26164749
• Reddy, C. R.; Ajaykumar, U.; Kolgave, D. H. Expeditious Access to Spiro-Fused 2,5-Cyclohexadienones via Thio(seleno)cyanative ipso-Cyclization. The Journal of organic chemistry 2020, 85, 15521–15531. doi:10.1021/acs.joc.0c02270
• Wang, Q.; Tian, P.; Cao, Z.-Y.; Zhang, H.; Jiang, C. Copper-Catalyzed Remote Direct Thiocyanation of Alkyl C(sp3)−H Bonds. Advanced Synthesis & Catalysis 2020, 362, 3851–3856. doi:10.1002/adsc.202000754
• Ferguson, D. J. Synthetic Studies of Vitamin B12. Organic Synthesis - A Nascent Relook [Working Title]; IntechOpen, 2020. doi:10.5772/intechopen.92104

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