Preactivation-based chemoselective glycosylations: A powerful strategy for oligosaccharide assembly

Scholarly Works

• Kosma, P. Chemical Synthesis of Complex Carbohydrates. Handbook of experimental pharmacology 2025, 288, 3–37. doi:10.1007/164_2025_747
• Yao, W.; Ye, X.-S. Donor Preactivation-Based Glycan Assembly: from Manual to Automated Synthesis. Accounts of chemical research 2024, 57, 1577–1594. doi:10.1021/acs.accounts.4c00072
• Zeng, C.; Zhang, H.; Zhu, D.; Yu, B. Convergent Synthesis of the Nonreducing Hexasaccharide Fragment and the Dodecasaccharide Scaffold of Marine Lipopolysaccharide Axinelloside A. Chemistry (Weinheim an der Bergstrasse, Germany) 2024, 30, e202400075. doi:10.1002/chem.202400075
• Chang, C.-W.; Lin, M.-H.; Chiang, T.-Y.; Wu, C.-H.; Lin, T.-C.; Wang, C.-C. Unraveling the promoter effect and the roles of counterion exchange in glycosylation reaction. Science advances 2023, 9, eadk0531. doi:10.1126/sciadv.adk0531
• Shit, P.; Sahaji, S.; Misra, A. K. Synthesis of selenoglycosides and selenium linked disaccharides using reductive cleavage of diselenides. Carbohydrate research 2022, 516, 108554. doi:10.1016/j.carres.2022.108554
• Li, T.; Li, T.; Zhang, Y.; Schmidt, R. R.; Peng, P. Preparation of Tea Aroma Precursor Glycosides: An Efficient and Sustainable Approach via Chemical Glycosidation. Journal of agricultural and food chemistry 2022, 70, 2320–2327. doi:10.1021/acs.jafc.1c07043
• Weldu, W. D.; Wang, C.-C. Rationalizing the Stereoelectronic Influence of Interglycosidic Bond Conformations on the Reactivity of 1,4-O-Linked Disaccharide Donors. The Journal of organic chemistry 2021, 86, 17906–17917. doi:10.1021/acs.joc.1c02207
• Cai, L.; Meng, L.; Zeng, J.; Wan, Q. Sequential activation of thioglycosides enables one-pot glycosylation. Organic Chemistry Frontiers 2021, 8, 3150–3165. doi:10.1039/d0qo01414a
• Chang, C.; Lin, M.; Chan, C.; Su, K.; Wu, C.; Lo, W.; Lam, S.; Cheng, Y.; Liao, P.; Wong, C.; Wang, C. Automated Quantification of Hydroxyl Reactivities: Prediction of Glycosylation Reactions. Angewandte Chemie 2021, 133, 12521–12531. doi:10.1002/ange.202013909
• Chang, C.-W.; Lin, M.-H.; Chan, C.-K.; Su, K.-Y.; Wu, C.-H.; Lo, W.-C.; Lam, S.; Cheng, Y.-T.; Liao, P.-H.; Wong, C.-H.; Wang, C.-C. Automated Quantification of Hydroxyl Reactivities: Prediction of Glycosylation Reactions. Angewandte Chemie (International ed. in English) 2021, 60, 12413–12423. doi:10.1002/anie.202013909
• Basu, N.; Ghosh, R. Recent chemical syntheses of bacteria related oligosaccharides using modern expeditious approaches. Carbohydrate research 2021, 507, 108295. doi:10.1016/j.carres.2021.108295
• Oscarson, S.; Cheallaigh, A. N. Comprehensive Glycoscience - Strategies in Oligosaccharide Synthesis. Comprehensive Glycoscience; Elsevier, 2021; pp 1–48. doi:10.1016/b978-0-12-819475-1.00075-4
• Mong, K.-K. T.; Cheng, K.-C.; Lu, I.-C.; Pan, C.-W.; Wang, Y.-F.; Shen, L.-C. Cascade In Situ Phosphorylation and One-Pot Glycosylation for Rapid Synthesis of Heptose-Containing Oligosaccharides. The Journal of organic chemistry 2020, 85, 16060–16071. doi:10.1021/acs.joc.0c01828
• Chang, C.-W.; Lin, M.-H.; Wu, C.-H.; Chiang, T.-Y.; Wang, C.-C. Mapping Mechanisms in Glycosylation Reactions with Donor Reactivity: Avoiding Generation of Side Products. The Journal of organic chemistry 2020, 85, 15945–15963. doi:10.1021/acs.joc.0c01313
• Sun, L.; Zhu, D.; Beverborg, L. O. G.; Wang, R.; Dang, Y.; Ma, M.; Li, W.; Yu, B. Synthesis and Antiproliferative Activities of OSW-1 Analogues Bearing 2”-O-p-Acylaminobenzoyl Residues†. Chinese Journal of Chemistry 2020, 38, 1091–1097. doi:10.1002/cjoc.202000110
• Gannedi, V.; Ali, A.; Singh, P. P.; Vishwakarma, R. A. Total Synthesis of Phospholipomannan of Candida albicans. The Journal of organic chemistry 2020, 85, 7757–7771. doi:10.1021/acs.joc.0c00402
• Sun, J.; Fang, J.; Xiao, X.; Cai, L.; Zhao, X.; Zeng, J.; Wan, Q. Total synthesis of tricolorin A via interrupted Pummerer reaction-mediated glycosylation and one-pot relay glycosylation. Organic & biomolecular chemistry 2020, 18, 3818–3822. doi:10.1039/d0ob00513d
• Underlin, E. N.; d'Errico, C.; Böhm, M. F.; Madsen, R. Synthesis of Glucuronoxylan Hexasaccharides by Preactivation-Based Glycosylations. European Journal of Organic Chemistry 2020, 2020, 3050–3058. doi:10.1002/ejoc.202000211
• Xiao, X.; Zeng, J.; Fang, J.; Sun, J.; Li, T.; Song, Z.; Cai, L.; Wan, Q. One-Pot Relay Glycosylation. Journal of the American Chemical Society 2020, 142, 5498–5503. doi:10.1021/jacs.0c00447
• Ding, Y.; Prasad, C. V. N. S. V.; Wang, B. Glycosylation on Unprotected or Partially Protected Acceptors. European Journal of Organic Chemistry 2020, 2020, 1784–1801. doi:10.1002/ejoc.201901675

Explore citations to this article at