Recent applications of chiral calixarenes in asymmetric catalysis

Scholarly Works

• Membrat, R.; Manick, A.-D.; Tlusty, M.; Lavaud, L.; Herbette, G.; Chentouf, S.; Naubron, J.-V.; Giordano, L.; Nuel, D.; Lhotak, P.; Martinez, A. Secondary Phosphine Oxide Grafted on an Inherently Chiral Calixarene: Synthesis, Resolution, Characterizations, and Catalytic Activity. The Journal of organic chemistry 2025, 90, 17380–17385. doi:10.1021/acs.joc.5c02171
• Bayrakdar, A.; Kart, H.; Elçin, S.; Ashfaq, M.; Mali, S. N.; Yasin, H. K. A.; Smerat, A. Concise experimental and DFT study of newly synthesized 5,17-di(2-antracenylazo)-25,27-[1,3-ethylene-bis(aminocarbonylmethoxy)]-26,28-dihydroxycalix[4]arene. Chemical Physics Impact 2025, 11, 100965. doi:10.1016/j.chphi.2025.100965
• Gong, X.; Zhang, L.; Liu, X.; Shi, M.; Zhang, M.; Yao, T.; Yan, Q.; Nan, J. Asymmetric Electrophilic Amination of Calix[4]arene Amines: Rapid Assembly of Inherently Chiral Diamine Frameworks. Organic letters 2025, 27, 12991–12996. doi:10.1021/acs.orglett.5c04041
• Yuan, M.; Xie, W.; Yang, X. Enantioselective synthesis of inherently chiral calix[4]arenes via asymmetric C-H bromination of phenols. Chinese Chemical Letters 2025, 112157. doi:10.1016/j.cclet.2025.112157
• Feng, J.; Xi, L.-L.; Liu, R.-R. Inherently Chiral Calix[4]Arene Derivatives: Concept and Enantioselective Synthesis. Chemistry (Weinheim an der Bergstrasse, Germany) 2025, 31, e02247. doi:10.1002/chem.202502247
• Wei, L.; Chen, Y.; Zhou, Q.; Wei, Z.; Tu, T.; Ren, S.; Chi, Y. R.; Zhang, X.; Yang, X. Carbene-Catalyzed Intramolecular Cyclization to Access Inherently Chiral Saddle-Shaped Lactones: Achiral Bases Alternate Product Chirality. Journal of the American Chemical Society 2025, 147, 30747–30756. doi:10.1021/jacs.5c05380
• Dočekal, V.; Lóška, L.; Kurčina, A.; Císařová, I.; Veselý, J. Desymmetric esterification catalysed by bifunctional chiral N-heterocyclic carbenes provides access to inherently chiral calix[4]arenes. Nature communications 2025, 16, 4443. doi:10.1038/s41467-025-59781-4
• Li, Z.-Y.; Li, T.; Wang, Z.; Zhao, Y.; Shi, J.; Sun, X.; Yang, K. Cycloaddition of epoxides and atmospheric CO2 in aqueous catalyzed by an upper-rim functionalized calix[4]arene organocatalyst. Chinese Chemical Letters 2025, 111352. doi:10.1016/j.cclet.2025.111352
• Yuan, M.; Xie, W.; Yu, S.; Liu, T.; Yang, X. Catalytic enantioselective synthesis of inherently chiral calix[4]arenes via organocatalyzed aromatic amination enabled desymmetrization. Nature communications 2025, 16, 3943. doi:10.1038/s41467-025-59221-3
• Saeednia, B.; Sragow, A. M.; Lin, Y.; Sheehan, C. J.; Metlay, A. S.; Gau, M. R.; Dye, S. A.; O'Konski, S. P.; Mallouk, T. E.; Dmochowski, I. J. Unusually air-stable copper(i) complexes showing high selectivity for carbon monoxide. Chemical science 2025, 16, 5058–5063. doi:10.1039/d5sc00237k
• Wang, M.; Li, T.; Shi, J.; Sun, X.; Yang, K.; Li, Z. Recent Advances in Calix[4]arene‐Catalyzed Synthesis of Five‐ and Six‐Membered Oxa‐ and Azacycles. European Journal of Organic Chemistry 2025, 28. doi:10.1002/ejoc.202401461
• Cunningham, L. Supramolecular Chemistry: An Enabling Tool for Asymmetric Catalysis. Synlett 2025, 36, 1189–1200. doi:10.1055/a-2513-2141
• Da, C.-S.; Du, Z.-H.; Wang, P. The Aldol Reaction: Organocatalytic Approach. Comprehensive Organic Synthesis; Elsevier, 2025; pp 250–336. doi:10.1016/b978-0-323-96025-0.00127-7
• Huang, S.; Yang, L.; Wang, L.; Yao, H. Research Progress and Application of Chiral Macrocycles in Supramolecular Catalysis. Chinese Journal of Organic Chemistry 2025, 45, 3624. doi:10.6023/cjoc202502040
• Karpus, A.; Yesypenko, O.; Daran, J.-C.; Voitenko, Z.; Manoury, E.; Kalchenko, V. Synthesis and organocatalytical evaluation of optically pure inherently chiral calix[4]arene phosphoric acids. Journal of Inclusion Phenomena and Macrocyclic Chemistry 2024, 105, 75–86. doi:10.1007/s10847-024-01267-9
• Sachdeva, G.; Rathi, K.; Rawat, V.; Verma, V. P. Exploring Sulphonated Calix[n]arenes as Catalysts in Organic Reactions. Asian Journal of Organic Chemistry 2024, 13. doi:10.1002/ajoc.202400361
• Qian, P.; Zhou, G.; Hu, J.; Wang, B.; Jiang, A.; Zhou, T.; Yuan, W.; Yao, Q.; Chen, J.; Kong, K.; Shi, B. Asymmetric Synthesis of Chiral Calix[4]arenes with Both Inherent and Axial Chirality via Cobalt‐Catalyzed Enantioselective Intermolecular C−H Annulation. Angewandte Chemie 2024, 136. doi:10.1002/ange.202412459
• Qian, P.-F.; Zhou, G.; Hu, J.-H.; Wang, B.-J.; Jiang, A.-L.; Zhou, T.; Yuan, W.-K.; Yao, Q.-J.; Chen, J.-H.; Kong, K.-X.; Shi, B.-F. Asymmetric Synthesis of Chiral Calix[4]arenes with Both Inherent and Axial Chirality via Cobalt-Catalyzed Enantioselective Intermolecular C-H Annulation. Angewandte Chemie (International ed. in English) 2024, 63, e202412459. doi:10.1002/anie.202412459
• Guajardo-Maturana, R.; Rodríguez-Kessler, P. L.; Muñoz-Castro, A. Benzene–Ni10S20 Interaction. Host–Guest Features and Nuclear Magnetic Resonance Patterns toward Prototypical Metal-Based Active Cavities. The Journal of Physical Chemistry C 2024, 128, 15549–15557. doi:10.1021/acs.jpcc.4c02856
• Jiang, Y.-F.; Tong, S.; Zhu, J.; Wang, M.-X. Inherently chiral nor-heteracalixarenes: design and synthesis via enantioselective intramolecular Suzuki-Miyaura reaction. Chemical science 2024, 15, 12517–12522. doi:10.1039/d4sc03506b

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