Unexpected polymorphism during a catalyzed mechanochemical Knoevenagel condensation

Scholarly Works

• Speight, I. R.; Ardila-Fierro, K. J.; Hernández, J. G.; Emmerling, F.; Michalchuk, A. A. L.; García, F.; Colacino, E.; Mack, J. Ball milling for mechanochemical reactions. Nature Reviews Methods Primers 2025, 5. doi:10.1038/s43586-025-00401-2
• Emmerling, F.; Michalchuk, A. A. Monitoring in situ Mechanochemical Reactions. Encyclopedia of Green Chemistry; Elsevier, 2025; pp 437–447. doi:10.1016/b978-0-443-15742-4.00126-5
• Ardila‐Fierro, K. J.; Hernández, J. G. Intermediates in Mechanochemical Reactions. Angewandte Chemie 2024, 136. doi:10.1002/ange.202317638
• Ardila-Fierro, K. J.; Hernández, J. G. Intermediates in Mechanochemical Reactions. Angewandte Chemie (International ed. in English) 2024, 63, e202317638. doi:10.1002/anie.202317638
• Wang, G.-W.; Wang, N.; Pan, H.; Shao, G.; Chen, J.-S. Mechanochemistry in organic synthesis. Introduction to Condensed Matter Chemistry; Elsevier, 2024; pp 73–103. doi:10.1016/b978-0-443-16140-7.00012-2
• Scheurrell, K.; B Martins, I. C.; Murray, C.; Emmerling, F. Exploring the role of solvent polarity in mechanochemical Knoevenagel condensation: in situ investigation and isolation of reaction intermediates. Physical chemistry chemical physics : PCCP 2023, 25, 23637–23644. doi:10.1039/d3cp02883f
• Paul, A.; Reese, M.; Goldhammer, T.; Schmalsch, C.; Weber, J.; Bannick, C. G. Spectroscopic evidence for adsorption of natural organic matter on microplastics. Applied Research 2023, 3. doi:10.1002/appl.202200126
• Michalchuk, A. A. L. The mechanochemical excitation of crystalline LiN3. Faraday discussions 2023, 241, 230–249. doi:10.1039/d2fd00112h
• Boldyreva, E. Spiers Memorial Lecture: Mechanochemistry, tribochemistry, mechanical alloying - retrospect, achievements and challenges. Faraday discussions 2023, 241, 9–62. doi:10.1039/d2fd00149g
• Guilherme Buzanich, A.; Cakir, C. T.; Radtke, M.; Haider, M. B.; Emmerling, F.; F M de Oliveira, P.; Michalchuk, A. A. L. Dispersive x-ray absorption spectroscopy for time-resolved in situ monitoring of mechanochemical reactions. The Journal of chemical physics 2022, 157, 214202. doi:10.1063/5.0130673
• Zänker, S.; Scholz, G.; Marquardt, J.; Emmerling, F. Structural changes in Ba‐compounds of different hardness induced by high‐energy ball milling – evidenced by 137Ba NMR and X‐ray powder diffraction. Zeitschrift für anorganische und allgemeine Chemie 2022, 648. doi:10.1002/zaac.202200026
• Michalchuk, A. A. L.; Emmerling, F. Time-Resolved In Situ Monitoring of Mechanochemical Reactions. Angewandte Chemie (International ed. in English) 2022, 61, e202117270. doi:10.1002/anie.202117270
• Michalchuk, A. A. L.; Emmerling, F. Zeitaufgelöste In‐Situ‐Untersuchungen von mechanochemischen Reaktionen. Angewandte Chemie 2022, 134. doi:10.1002/ange.202117270
• Jose, A.; Guest, D.; LeGay, R.; Tizzard, G. J.; Coles, S. J.; Derveni, M.; Wright, E.; Marrison, L.; Lee, A. A.; Morris, A.; Robinson, M.; von Delft, F.; Fearon, D.; Koekemoer, L.; Matviuk, T.; Aimon, A.; Schofield, C. J.; Malla, T. R.; London, N.; Greenland, B. W.; Bagley, M. C.; Spencer, J.; The Covid Moonshot Consortium. Expanding the Repertoire of Low-Molecular-Weight Pentafluorosulfanyl-Substituted Scaffolds. ChemMedChem 2022, 17, e202100641. doi:10.1002/cmdc.202100641
• Michalchuk, A. A. L.; Kabelitz, A.; Emmerling, F. Methods and Principles in Medicinal Chemistry; Wiley, 2021; pp 215–248. doi:10.1002/9783527823048.ch4-8
• Lukin, S.; Užarević, K.; Halasz, I. Raman spectroscopy for real-time and in situ monitoring of mechanochemical milling reactions. Nature protocols 2021, 16, 3492–3521. doi:10.1038/s41596-021-00545-x
• Michalchuk, A. A. L.; Boldyreva, E. V.; Belenguer, A. M.; Emmerling, F.; Boldyrev, V. V. Tribochemistry, Mechanical Alloying, Mechanochemistry: What is in a Name?. Frontiers in chemistry 2021, 9, 685789. doi:10.3389/fchem.2021.685789
• Wilke, M.; Gawryluk, D. J.; Casati, N. Metastability and Seeding Effects in the Mechanochemical Hybrid Lead(II) Iodide Formation. Chemistry (Weinheim an der Bergstrasse, Germany) 2021, 27, 5944–5955. doi:10.1002/chem.202004431
• Michalchuk, A. A. L.; Kabelitz, A.; Emmerling, F. Monitoring mechanochemical processes in situ and in real time. Nontraditional Activation Methods in Green and Sustainable Applications; Elsevier, 2021; pp 369–419. doi:10.1016/b978-0-12-819009-8.00004-9
• Oliveira, P. F.; Michalchuk, A. A. L.; Marquardt, J.; Feiler, T.; Prinz, C.; Torresi, R. M.; Camargo, P. H. C.; Emmerling, F. Investigating the role of reducing agents on mechanosynthesis of Au nanoparticles. CrystEngComm 2020, 22, 6261–6267. doi:10.1039/d0ce00826e

Explore citations to this article at