Halide metathesis in overdrive: mechanochemical synthesis of a heterometallic group 1 allyl complex

Ross F. Koby, Nicholas R. Rightmire, Nathan D. Schley, Timothy P. Hanusa and William W. Brennessel
Beilstein J. Org. Chem. 2019, 15, 1856–1863. https://doi.org/10.3762/bjoc.15.181

Supporting Information

Crystallographic data for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as CCDC 1897690 ([KCsA'2]), 1897691 ([(C6H6)KA']), and 1897692 ([(toluene)KA']). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44)1223-336-033; email: deposit@ccdc.cam.ac.uk).

Supporting Information File 1: Experimental and computational details; crystal data and summary of X–ray data collection.
Format: PDF Size: 668.4 KB Download
Supporting Information File 2: Coordinates of DFT-optimized structures.
Format: XYZ Size: 15.4 KB Download

Cite the Following Article

Halide metathesis in overdrive: mechanochemical synthesis of a heterometallic group 1 allyl complex
Ross F. Koby, Nicholas R. Rightmire, Nathan D. Schley, Timothy P. Hanusa and William W. Brennessel
Beilstein J. Org. Chem. 2019, 15, 1856–1863. https://doi.org/10.3762/bjoc.15.181

How to Cite

Koby, R. F.; Rightmire, N. R.; Schley, N. D.; Hanusa, T. P.; Brennessel, W. W. Beilstein J. Org. Chem. 2019, 15, 1856–1863. doi:10.3762/bjoc.15.181

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.
Format: PNG Size: 818.1 KB Download

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Koby, R. F.; Schley, N. D.; Hanusa, T. P. Di(indenyl)beryllium. Angewandte Chemie (International ed. in English) 2021, 60, 21174–21178. doi:10.1002/anie.202107980
  • Koby, R. F.; Schley, N. D.; Hanusa, T. P. Di(indenyl)beryllium. Angewandte Chemie 2021, 133, 21344–21348. doi:10.1002/ange.202107980
  • Fiss, B. G.; Richard, A. J.; Douglas, G.; Kojic, M.; Friščić, T.; Moores, A. Mechanochemical methods for the transfer of electrons and exchange of ions: inorganic reactivity from nanoparticles to organometallics. Chemical Society reviews 2021, 50, 8279–8318. doi:10.1039/d0cs00918k
  • Koby, R. F.; Doerr, A. M.; Rightmire, N. R.; Schley, N. D.; Long, B. K.; Hanusa, T. P. An η3‐Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex. Angewandte Chemie 2020, 132, 9629–9635. doi:10.1002/ange.201916410
  • Koby, R. F.; Doerr, A. M.; Rightmire, N. R.; Schley, N. D.; Long, B. K.; Hanusa, T. P. An η 3 -Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex. Angewandte Chemie (International ed. in English) 2020, 59, 9542–9548. doi:10.1002/anie.201916410
Other Beilstein-Institut Open Science Activities