Halide metathesis in overdrive: mechanochemical synthesis of a heterometallic group 1 allyl complex

Ross F. Koby, Nicholas R. Rightmire, Nathan D. Schley, Timothy P. Hanusa and William W. Brennessel

Beilstein J. Org. Chem. 2019, 15, 1856–1863. doi:10.3762/bjoc.15.181

Supporting Information

Crystallographic data for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as CCDC 1897690 ([KCsA'2]), 1897691 ([(C6H6)KA']), and 1897692 ([(toluene)KA']). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44)1223-336-033; email: deposit@ccdc.cam.ac.uk).

Supporting Information File 1: Experimental and computational details; crystal data and summary of X–ray data collection.
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Supporting Information File 2: Coordinates of DFT-optimized structures.
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