Rearrangement of o-(pivaloylaminomethyl)benzaldehydes: an experimental and computational study

Csilla Hargitai, Györgyi Koványi-Lax, Tamás Nagy, Péter Ábrányi-Balogh, András Dancsó, Gábor Tóth, Judit Halász, Angéla Pandur, Gyula Simig and Balázs Volk

Beilstein J. Org. Chem. 2020, 16, 1636–1648. doi:10.3762/bjoc.16.136

Supporting Information

Detailed NMR studies (1H NMR, 13C NMR, DeptQ, Dept-135, edHSQC, selective HSQC, HMBC, selective HMBC, NOESY, 1H,1H-COSY, one-dimensional selective NOE, selective TOCSY spectra) of new compounds; HRMS spectra of compounds 23a and 23b; coordinates and energy values of the computed structures; cif files and structure report files of compounds 3a, 3b, 8b, 23a, 23b.

Supporting Information File 1: Detailed NMR studies.
Format: PDF Size: 5.5 MB Download
Supporting Information File 2: Crystallographic information files for compounds 3a, 3b, 8b, 23a, and 23b.
Format: ZIP Size: 9.1 MB Download

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.

Format: PNG Size: 185.7 KB Download
Back To Article

Latest Articles

Design, synthesis and application of carbazole macrocycles in anion sensors

  1. Alo Rüütel,
  2. Ville Yrjänä,
  3. Sandip A. Kadam,
  4. Indrek Saar,
  5. Mihkel Ilisson,
  6. Astrid Darnell,
  7. Kristjan Haav,
  8. Tõiv Haljasorg,
  9. Lauri Toom,
  10. Johan Bobacka and
  11. Ivo Leito
  • Full Research Paper
  • Published 04 Aug 2020

Beilstein J. Org. Chem. 2020, 16, 1901–1914, doi:10.3762/bjoc.16.157

Natural dolomitic limestone-catalyzed synthesis of benzimidazoles, dihydropyrimidinones, and highly substituted pyridines under ultrasound irradiation

  1. Kumar Godugu,
  2. Venkata Divya Sri Yadala,
  3. Mohammad Khaja Mohinuddin Pinjari,
  4. Trivikram Reddy Gundala,
  5. Lakshmi Reddy Sanapareddy and
  6. Chinna Gangi Reddy Nallagondu
  • Full Research Paper
  • Published 03 Aug 2020

Beilstein J. Org. Chem. 2020, 16, 1881–1900, doi:10.3762/bjoc.16.156

  • Full Research Paper
  • Published 31 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1875–1880, doi:10.3762/bjoc.16.155

  • Full Research Paper
  • Published 29 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1869–1874, doi:10.3762/bjoc.16.154

On the hydrolysis of diethyl 2-(perfluorophenyl)malonate

  1. Ilya V. Taydakov and
  2. Mikhail A. Kiskin
  • Letter
  • Published 28 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1863–1868, doi:10.3762/bjoc.16.153

Beilstein J. Org. Chem. 2020, 16, 1853–1862, doi:10.3762/bjoc.16.152

  • Full Research Paper
  • Published 23 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1837–1852, doi:10.3762/bjoc.16.151

  • Full Research Paper
  • Published 22 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1830–1836, doi:10.3762/bjoc.16.150

Synthesis and highly efficient light-induced rearrangements of diphenylmethylene(2-benzo[b]thienyl)fulgides and fulgimides

  1. Vladimir P. Rybalkin,
  2. Sofiya Yu. Zmeeva,
  3. Lidiya L. Popova,
  4. Valerii V. Tkachev,
  5. Andrey N. Utenyshev,
  6. Olga Yu. Karlutova,
  7. Alexander D. Dubonosov,
  8. Vladimir A. Bren,
  9. Sergey M. Aldoshin and
  10. Vladimir I. Minkin
  • Full Research Paper
  • Published 22 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1820–1829, doi:10.3762/bjoc.16.149

  • Full Research Paper
  • Published 21 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1805–1819, doi:10.3762/bjoc.16.148

Latest Thematic Issues

Copper-catalyzed reactions for organic synthesis


Gwilherm Evano and Olivier Riant

2019 Show Issue

Molecular switches


Wiktor Szymanski and Stefan Hecht

2019 Show Issue

Terpenes


Jeroen S. Dickschat

2019 Show Issue

Reactive intermediates – carbocations


Dean J. Tantillo and Stephanie R. Hare

2018 Show Issue

Keep Informed

RSS Feed

Subscribe to our Latest Articles RSS Feed.

Subscribe

Follow the Beilstein-Institut

LinkedIn

Twitter: @BeilsteinInst