Synthetic approaches to bowl-shaped π-conjugated sumanene and its congeners

Scholarly Works

• Xie, M.-L.; Chen, R.-H.; Ma, S.-J.; Li, W.-Q.; Tian, W.-Q.; Li, C.; Lefkidis, G.; Hübner, W.; Jin, W. First-principles study of electronic structures, magnetic properties, ultrafast spin dynamics, and spin logic gates in cobalt-π-bowl complexes. Physical chemistry chemical physics : PCCP 2026, 28, 20984–20993. doi:10.1039/d6cp00817h
• Ikeno, A.; Hayakawa, M.; Masunaga, N.; Ueda, A.; Hatakeyama, T. Selenium-induced curvature control enables polymorphism in borabuckybowls. Chemical science 2026, 17, 15727–15734. doi:10.1039/d6sc03964b
• Kulczyk, S.; Stawarska, A.; Małkowska, A.; Sassak, H.; Sakurai, H.; Bamburowicz-Klimkowska, M.; Kasprzak, A. Sumanene meets 5-fluorouracil: curved π-conjugated biointerfaces through covalent and supramolecular integration. Organic & biomolecular chemistry 2026. doi:10.1039/d6ob00812g
• Ażgin-Gontarek, J.; Wróblewski, W.; Sakurai, H.; Kasprzak, A. Switching cation selectivity via steric tuning in sumanene-based receptors. Chemical communications (Cambridge, England) 2026, 62, 14032–14036. doi:10.1039/d6cc02933g
• Cai, H.-M.; Chen, Z.-H.; Li, R.; Zhong, Y.-M.; Deng, Z.-H.; Yang, T.-S.; Song, Z.-Y.; Guo, X.-Q.; Sun, Q.-F. Highly selective o-xylene separation enabled by a bowl-shaped phosphangulene oxide-based molecular cage. Science China Chemistry 2026. doi:10.1007/s11426-026-3455-2
• Yang, S.; Shao, X. Buckybowl-based functional materials: from molecular architecture to optoelectronic functions. Journal of Materials Chemistry C 2026, 14, 11383–11435. doi:10.1039/d6tc01048b
• Nagai, M.; Hayakawa, M.; Nakatsuka, S.; Okano, T.; Oya, H.; Ikeno, A.; Hatakeyama, T. Dual‐Phosphorus, Dual‐Nitrogen‐Embedded Corannulene: Synthesis, Structure, and Electronic Coupling. ChemistryEurope 2026, 4. doi:10.1002/ceur.70302
• Kasprzak, A. Buckybowls at the Biointerface: Sumanene and Corannulene as Emerging Platforms for Medicinal Chemistry. ChemMedChem 2026, 21, e202500880. doi:10.1002/cmdc.202500880
• Xu, G.; Yang, Y.; Chen, Q.; Xie, S.; Zhang, Q. Bowl‐Shaped Conjugated Organic Semiconductors: From Structural Design, Molecular Assembly to Device Applications. Advanced Functional Materials 2026, 36. doi:10.1002/adfm.202528875
• Chai, L.; Li, K.; Xing, J.-F.; Zhao, X.-J.; Tan, Y.-Z. Curved Nanographene Featuring Two sp3 Stereocenters via Oxidative Cyclodehydrogenation with Aryl Rearrangement. Organic letters 2025, 27, 11105–11110. doi:10.1021/acs.orglett.5c03555
• Kurowski, Ł.; Cyniak, J. S.; Sakurai, H.; Kasprzak, A. Sumanene-Conjugated Poly(amidoamine) Dendrimer for the Detection of Metal Cations in Aqueous Solution. ChemPlusChem 2025, 90, e202500426. doi:10.1002/cplu.202500426
• Kahar, N.; Bhatt, G. J.; Purohit, A. C.; Deota, P. T. Syntheses, Reactivity, and Structures of Cyclotrimeric Ring Systems with Magic Display of Three‐Fold Symmetry. ChemistrySelect 2025, 10. doi:10.1002/slct.202405703
• Zhang, W.; Ding, Y.; Yu, S.; Lyu, J.; Yu, J.; Li, J.; Zhao, X.; Feng, L.; Wang, J.; Zhou, Z.; Wang, Q. Highly Strained Electron‐Rich Molecular Bowl and Nanographene. Angewandte Chemie 2025, 137. doi:10.1002/ange.202425355
• Zhang, W.; Ding, Y.; Yu, S.; Lyu, J.; Yu, J.; Li, J.; Zhao, X.; Feng, L.; Wang, J.; Zhou, Z.; Wang, Q. Highly Strained Electron-Rich Molecular Bowl and Nanographene. Angewandte Chemie (International ed. in English) 2025, 64, e202425355. doi:10.1002/anie.202425355
• Singh, P.; Maji, S.; Chatterjee, I.; Vaishnav, J.; Sakurai, H.; Ampapathi, R. S.; Panda, G. Bucky‐Bowl‐Derived Unnatural Amino Acids and Peptides: Synthesis and Substituent Effect on Bowl Inversion Dynamics and Electronic Structure. ChemistrySelect 2025, 10. doi:10.1002/slct.202500744
• Chen, X.-L.; Yu, S.-Q.; Liang, J.-Q.; Huang, X.; Gong, H.-Y. Nitrogen-containing polycyclic aromatic hydrocarbons (PAHs) with bowl-shaped structures: synthesis, architecture, and applications. Organic Chemistry Frontiers 2025, 12, 1340–1354. doi:10.1039/d4qo01934b
• Song, W.; Shao, X. Buckybowl-Based Fullerene Receptors. Chemistry (Weinheim an der Bergstrasse, Germany) 2024, 31, e202403383. doi:10.1002/chem.202403383
• Wu, G.-Y.; Huang, C.-L.; Kang, H.-W.; Ou, W.-T.; Ho, Y.-S.; Cheng, M.-J.; Wu, Y.-T. exo-6b2-Methyl-Substituted Pentabenzocorannulene: Synthesis, Structural Analysis, and Properties. Angewandte Chemie (International ed. in English) 2024, 63, e202408321. doi:10.1002/anie.202408321
• Wu, G.; Huang, C.; Kang, H.; Ou, W.; Ho, Y.; Cheng, M.; Wu, Y. exo‐6b2‐Methyl‐Substituted Pentabenzocorannulene: Synthesis, Structural Analysis, and Properties. Angewandte Chemie 2024, 136. doi:10.1002/ange.202408321
• Kasprzak, A. Supramolecular Chemistry of Sumanene. Angewandte Chemie 2024, 136. doi:10.1002/ange.202318437

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