Sustainable manganese catalysis for late-stage C–H functionalization of bioactive structural motifs

Scholarly Works

• García-Viada, A.; Carretero, J. C.; Adrio, J.; Rodríguez, N. Insights into the mechanism of 3d transition-metal-catalyzed directed C(sp3)-H bond functionalization reactions. Chemical Society reviews 2025, 54, 4353–4390. doi:10.1039/d4cs00657g
• Pilkington, R. L.; Priebbenow, D. L. Acylsilanes as Weakly Coordinating Directing Groups for Metal-Catalyzed C–H Functionalization. ACS Catalysis 2025, 15, 6881–6894. doi:10.1021/acscatal.5c00794
• Baumann, B. N.; Dam, P.; Rabeah, J.; Kubis, C.; Brückner, A.; Jiao, H.; Hapke, M. Photochemical Manganese-Catalyzed [2 + 2 + 2] Cycloaddition Reactions. ACS catalysis 2025, 15, 5718–5730. doi:10.1021/acscatal.5c00349
• Kim, Y.; Jang, W. J. Recent advances in electrochemical copper catalysis for modern organic synthesis. Beilstein journal of organic chemistry 2025, 21, 155–178. doi:10.3762/bjoc.21.9
• Anusree, G.; Devi, P. S.; Anilkumar, G. Recent Advances and Prospects in Manganese‐Catalyzed C−H Activation. Advanced Synthesis & Catalysis 2024, 366, 3963–3999. doi:10.1002/adsc.202400611
• Rungthanaphatsophon, P.; Rath, N. P.; Neely, J. M. Bis(phenanthrolinyl)amine manganese complexes with pseudo-trigonal prismatic geometry. Inorganica Chimica Acta 2023, 556, 121666. doi:10.1016/j.ica.2023.121666
• Ablyasova, O. S.; Guo, M.; Zamudio-Bayer, V.; Kubin, M.; Gitzinger, T.; da Silva Santos, M.; Flach, M.; Timm, M.; Lundberg, M.; Lau, J. T.; Hirsch, K. Electronic Structure of the Complete Series of Gas-Phase Manganese Acetylacetonates by X-ray Absorption Spectroscopy. The journal of physical chemistry. A 2023, 127, 7121–7131. doi:10.1021/acs.jpca.3c02794
• Sengupta, S.; Pabbaraja, S.; Mehta, G. C-H modification of natural products: a minimalist enabling tactic for drug discovery, API processing and bioconjugation. Chemical communications (Cambridge, England) 2023, 59, 9445–9456. doi:10.1039/d3cc01644g
• Montgomery, A. P.; Joyce, J. M.; Danon, J. J.; Kassiou, M. An update on late-stage functionalization in today's drug discovery. Expert opinion on drug discovery 2023, 18, 597–613. doi:10.1080/17460441.2023.2205635
• Kasper, J. B.; Vicens, L.; de Roo, C. M.; Hage, R.; Costas, M.; Browne, W. R. Reversible Deactivation of Manganese Catalysts in Alkene Oxidation and H2O2 Disproportionation. ACS Catalysis 2023, 13, 6403–6415. doi:10.1021/acscatal.3c00866
• Parmar, D.; Sharma, U. doi:10.1002/9783527834242.chf0122
• John, S. E.; Bora, D.; Shankaraiah, N. Ru(II)-Catalyzed regioselective carbene insertion into β-carbolines and isoquinolines. Organic & biomolecular chemistry 2022, 20, 5852–5860. doi:10.1039/d2ob00946c
• Das, K. K.; Ghosh, A. K.; Hajra, A. Late-stage ortho-C-H alkenylation of 2-arylindazoles in aqueous medium by Manganese(i)-catalysis. RSC advances 2022, 12, 19412–19416. doi:10.1039/d2ra03547b
• Xin, Y.; Yuan, J.; Liu, Y.; Zhao, Z.; Du, B.; Xing, F.; Zhang, F. 2D Manganese Nanosheets with Optical-Limiting Behavior for Precision Instrument and Eye Protection. ACS Applied Nano Materials 2022, 5, 8080–8088. doi:10.1021/acsanm.2c01216
• Jei, B. B.; Yang, L.; Ackermann, L. Selective Labeling of Peptides with o-Carboranes via Manganese(I)-Catalyzed C-H Activation. Chemistry (Weinheim an der Bergstrasse, Germany) 2022, 28, e202200811. doi:10.1002/chem.202200811
• He, X.; Zhao, Y.; Zhang, Z.; Shen, X. Tuning the Reactivity of Alkoxyl Radicals from Cyclization to 1,2-Silyl Transfer: Stereoselective Synthesis of β-Substituted Cycloalcohols. Organic letters 2022, 24, 1991–1995. doi:10.1021/acs.orglett.2c00428
• Kaplaneris, N.; Ackermann, L. Earth-abundant 3d transition metals on the rise in catalysis. Beilstein journal of organic chemistry 2022, 18, 86–88. doi:10.3762/bjoc.18.8
• Choi, I.; Struwe, J.; Ackermann, L. C-H activation by immobilized heterogeneous photocatalysts. Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 2021, 20, 1–10. doi:10.1007/s43630-021-00132-9

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