Strategies to access the [5-8] bicyclic core encountered in the sesquiterpene, diterpene and sesterterpene series
Cécile Alleman, Charlène Gadais, Laurent Legentil and François-Hugues Porée
Beilstein J. Org. Chem. 2023, 19, 245–281.
https://doi.org/10.3762/bjoc.19.23
Chemical Information
Calculated using the Chemistry Development Kit 2.12
| Molecular Formula | C23H40O3Si |
| Molecular Weight | 392.65 g/mol |
| Exact Mass | 392.2747 Da |
| InChI |
InChI=1S/C23H40O3Si/c1-9-14-17-19-18(15-23(7,8)21(19)25-22(17)24)20(16(6)10-2)26-27(11-3,12-4)13-5/h9-10,16-21H,1-2,11-15H2,3-8H3/t16-,17-,18?,19?,20+,21?/m0/s1
|
| InChIKey |
DARKFTZZLVMGDE-WVLKLMEGSA-N
|
| SMILES |
C=CC[C@H]1C2C(CC(C)(C)C2OC1=O)[C@@H]([C@@H](C)C=C)O[Si](CC)(CC)CC
|
| Number of Atoms | 67 |
| Number of H-Bond Acceptors | 3 |
| Number of H-Bond Donors | 0 |
| Atoms in the Largest π-System | 3 |
| XLogP | 6.4 |
