Strategies to access the [5-8] bicyclic core encountered in the sesquiterpene, diterpene and sesterterpene series
Cécile Alleman, Charlène Gadais, Laurent Legentil and François-Hugues Porée
Beilstein J. Org. Chem. 2023, 19, 245–281.
https://doi.org/10.3762/bjoc.19.23
Chemical Information
Calculated using the Chemistry Development Kit 2.12
| Molecular Formula | C28H41BrO3Si2 |
| Molecular Weight | 561.70 g/mol |
| Exact Mass | 560.1777 Da |
| InChI |
InChI=1S/C28H41BrO3Si2/c1-27(2,3)33(7,8)31-20-23-25(19-24(30)26(23)29)32-34(28(4,5)6,21-15-11-9-12-16-21)22-17-13-10-14-18-22/h9-18,23,25-26H,19-20H2,1-8H3/t23-,25-,26?/m0/s1
|
| InChIKey |
GGZVGHVIDFDQQT-BRVRNLPISA-N
|
| SMILES |
CC(C)(C)[Si](C)(C)OC[C@H]1[C@H](CC(=O)C1Br)O[Si](C2=CC=CC=C2)(C3=CC=CC=C3)C(C)(C)C
|
| Number of Atoms | 75 |
| Number of H-Bond Acceptors | 3 |
| Number of H-Bond Donors | 0 |
| Atoms in the Largest π-System | 6 |
| XLogP | 6.3 |
