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Strategies to access the [5-8] bicyclic core encountered in the sesquiterpene, diterpene and sesterterpene series

Cécile Alleman, Charlène Gadais, Laurent Legentil and François-Hugues Porée

Beilstein J. Org. Chem. 2023, 19, 245–281. https://doi.org/10.3762/bjoc.19.23

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Chemical structure [C<sub>20</sub>H<sub>33</sub>]<sup>+</sup>

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Extracted from

Scheme 51

Chemical Information

Calculated using the Chemistry Development Kit 2.12

Property Name	Property Value
Molecular Formula	[C₂₀H₃₃]⁺
Molecular Weight	273.48 g/mol
Exact Mass	273.2582 Da
InChI	InChI=1S/C20H33/c1-15(2)18-12-14-20(5)13-11-17(4)8-6-7-16(3)9-10-19(18)20/h7,11,18-19H,6,8-10,12-14H2,1-5H3/q+1/b16-7+,17-11+/t18-,19+,20+/m1/s1
InChIKey	JPOGHMJLRHSFSK-JFZLUAFOSA-N
SMILES	C[C+](C)[C@H]1CC[C@]2(C)C/C=C(\C)/CC/C=C(\C)/C([H])([H])C[C@@]12[H]
Number of Atoms	53
Number of H-Bond Acceptors	0
Number of H-Bond Donors	0
Atoms in the Largest π-System	2
XLogP	8.7

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