Strategies to access the [5-8] bicyclic core encountered in the sesquiterpene, diterpene and sesterterpene series
Cécile Alleman, Charlène Gadais, Laurent Legentil and François-Hugues Porée
Beilstein J. Org. Chem. 2023, 19, 245–281.
https://doi.org/10.3762/bjoc.19.23
Chemical Information
Calculated using the Chemistry Development Kit 2.12
| Molecular Formula | C19H34O2Si |
| Molecular Weight | 322.56 g/mol |
| Exact Mass | 322.2328 Da |
| InChI |
InChI=1S/C19H34O2Si/c1-18(2,3)22(6,7)21-17-16-11-9-8-10-15(20)12-14(16)13-19(17,4)5/h9,11,14,16-17H,8,10,12-13H2,1-7H3/b11-9-/t14-,16-,17+/m0/s1
|
| InChIKey |
KBQUMWFQTNENQY-MWZSJHEOSA-N
|
| SMILES |
CC(C)(C)[Si](C)(C)O[C@@H]1[C@@]2([H])/C=C\CCC(=O)C[C@@]2([H])CC1(C)C
|
| Number of Atoms | 56 |
| Number of H-Bond Acceptors | 2 |
| Number of H-Bond Donors | 0 |
| Atoms in the Largest π-System | 2 |
| XLogP | 4.6 |
