Strategies to access the [5-8] bicyclic core encountered in the sesquiterpene, diterpene and sesterterpene series
Cécile Alleman, Charlène Gadais, Laurent Legentil and François-Hugues Porée
Beilstein J. Org. Chem. 2023, 19, 245–281.
https://doi.org/10.3762/bjoc.19.23
Chemical Information
Calculated using the Chemistry Development Kit 2.12
| Molecular Formula | C20H30O4Si |
| Molecular Weight | 362.54 g/mol |
| Exact Mass | 362.1913 Da |
| InChI |
InChI=1S/C20H30O4Si/c1-20(2)23-18-13-10-6-8-12-9-7-11-14(25(3,4)5)15(12)16(21)17(13)22-19(18)24-20/h7,9,12-13,17-19H,6,8,10-11H2,1-5H3/t12-,13+,17-,18+,19+/m0/s1
|
| InChIKey |
VJCCHYKXGRMEBL-ZGXYDKCCSA-N
|
| SMILES |
CC1(C)O[C@@H]2[C@]3([H])CCC[C@@]4([H])C=CCC(=C4C(=O)[C@@]3([H])O[C@@H]2O1)[Si](C)(C)C
|
| Number of Atoms | 55 |
| Number of H-Bond Acceptors | 4 |
| Number of H-Bond Donors | 0 |
| Atoms in the Largest π-System | 4 |
| XLogP | 3.7 |
