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Strategies to access the [5-8] bicyclic core encountered in the sesquiterpene, diterpene and sesterterpene series

Cécile Alleman, Charlène Gadais, Laurent Legentil and François-Hugues Porée

Beilstein J. Org. Chem. 2023, 19, 245–281. https://doi.org/10.3762/bjoc.19.23

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Chemical structure C<sub>21</sub>H<sub>42</sub>OSi<sub>2</sub>

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Extracted from

Scheme 21

Chemical Information

Calculated using the Chemistry Development Kit 2.12

Property Name	Property Value
Molecular Formula	C₂₁H₄₂OSi₂
Molecular Weight	366.73 g/mol
Exact Mass	366.2774 Da
InChI	InChI=1S/C21H42OSi2/c1-17-10-13-21(22-24(7,8)9)14-18(16-23(4,5)6)11-12-20(2,3)15-19(17)21/h11,17,19H,10,12-16H2,1-9H3/b18-11+/t17-,19+,21+/m0/s1
InChIKey	YMNXLEATGDPPRH-ONNKDYMMSA-N
SMILES	C[C@H]1CC[C@]2(C/C(=C\CC(C)(C)C[C@]12[H])/C[Si](C)(C)C)O[Si](C)(C)C
Number of Atoms	66
Number of H-Bond Acceptors	1
Number of H-Bond Donors	0
Atoms in the Largest π-System	2
XLogP	7.4

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