Cite the Following Article
Transition-metal-catalyzed C–H bond activation as a sustainable strategy for the synthesis of fluorinated molecules: an overview
Louis Monsigny, Floriane Doche and Tatiana Besset
Beilstein J. Org. Chem. 2023, 19, 448–473.
https://doi.org/10.3762/bjoc.19.35
How to Cite
Monsigny, L.; Doche, F.; Besset, T. Beilstein J. Org. Chem. 2023, 19, 448–473. doi:10.3762/bjoc.19.35
Download Citation
Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window
below.
Citation data in RIS format can be imported by all major citation management software, including EndNote,
ProCite, RefWorks, and Zotero.
Presentation Graphic
| Picture with graphical abstract, title and authors for social media postings and presentations. | ||
| Format: PNG | Size: 9.9 MB | Download |
Citations to This Article
Up to 20 of the most recent references are displayed here.
Scholarly Works
- Belnome, F.; Fehér, P. P.; Stirling, A.; Németh, C. G.; Hergert, T.; Keserű, G. M.; Ábrányi-Balogh, P. Versatile Palladium-Catalyzed C-H Arylation of Fluoroarenes with 2-Chloropyridine Derivatives. Chemistry (Weinheim an der Bergstrasse, Germany) 2025, e02723. doi:10.1002/chem.202502723
- Zhang, C.; Shen, Y.-T.; Xia, N.-X.; Zhou, X.-S.; Yang, L.-B.; Hu, J.; Li, Y.-M. Cascade cyclization/fluoromethylthiolation of alkynes, unsaturated α-bromocarbonyls and PhSO2SRF. Organic Chemistry Frontiers 2025, 12, 5265–5270. doi:10.1039/d5qo00585j
- Barik, P.; Sahoo, S.; Das, U.; Nanda, S. K. Photo/electro-catalytic stereo/enantioselective cross aza-pinacol coupling: synthesis of chiral amino alcohols. Chemical communications (Cambridge, England) 2025, 61, 11581–11596. doi:10.1039/d5cc03477a
- Galkin, K. I.; Sandulenko, I. V. Linking Fluorine with Bio-Derived Furfural: Aiming Towards More Sustainable Fluorinated Polymers and Drugs. Molecules (Basel, Switzerland) 2025, 30, 2305. doi:10.3390/molecules30112305
- Rzayev, J.; Jubault, P.; Besset, T. Copper-Catalyzed Regioselective Meta C─H Bond Olefination of Anilides. Chemistry (Weinheim an der Bergstrasse, Germany) 2025, 31, e202500992. doi:10.1002/chem.202500992
- Buttard, F.; Besset, T. Modern tools for the functionalization of C(sp3) centers by catalysis. Comptes Rendus. Chimie 2025, 28, 27–35. doi:10.5802/crchim.338
- Laga, E.; Nieto, S.; Cativiela, C.; Urriolabeitia, E. P. o-Halogenation and -Alkoxylation of Phenylglycine Derivatives by Pd-Mediated C-H Functionalization: Scope and Limitations. Molecules (Basel, Switzerland) 2025, 30, 236. doi:10.3390/molecules30020236
- Ajay, C.; Balasubramanian, S.; Subba Reddy, B. V. Rh(III)-Catalyzed Sequential ortho-C-H Bond Annulation and Desulfonylation of 3-Aryl-2H-benzo[e][1,2,4]thiadiazine-1,1-dioxides: Access to 1-Aminoisoquinolines. Chemistry, an Asian journal 2024, 19, e202400723. doi:10.1002/asia.202400723
- Kikushima, K.; Tsuda, T.; Miyamoto, N.; Kita, Y.; Dohi, T. Borate-mediated aryl polyfluoroalkoxylation under transition-metal-free conditions. Chemical communications (Cambridge, England) 2024, 60, 10552–10555. doi:10.1039/d4cc04008b
- Xiao, M.-M.; Hua, M.-Q.; Mou, F.-Y.; Xiong, H.-Y. Visible-light-induced Ir-catalyzed site-selective C−H trifluoromethylation of 3-substituted 1,2-benzoxazoles. Chemistry of Heterocyclic Compounds 2024, 60, 299–303. doi:10.1007/s10593-024-03336-w
- Capdevila, L.; Derks, M. T. G. M.; Montilla, M.; Luis, J. M.; Roithová, J.; Ribas, X. Direct 2,2,2‐Trifluoro and 2,2‐Difluoroethoxylation of a Model Macrocyclic Ar−H Substrate via Ni‐Catalysis. ChemistryEurope 2024, 2. doi:10.1002/ceur.202400023
- Dupommier, D.; Vuagnat, M.; Rzayev, J.; Roy, S.; Jubault, P.; Besset, T. Site-Selective Ortho/Ipso C-H Difunctionalizations of Arenes using Thianthrene as a Leaving Group. Angewandte Chemie (International ed. in English) 2024, 63, e202403950. doi:10.1002/anie.202403950
- Dupommier, D.; Vuagnat, M.; Rzayev, J.; Roy, S.; Jubault, P.; Besset, T. Site‐Selective Ortho/Ipso C−H Difunctionalizations of Arenes using Thianthrene as a Leaving Group. Angewandte Chemie 2024, 136. doi:10.1002/ange.202403950
- Buttard, F.; Vigier, J.; Lebel, H.; Besset, T. C‐Centered radical intermediates for C(sp3)‐H bonds functionalization: An emerging approach towards alkyl thiocyanates. European Journal of Organic Chemistry 2024, 27. doi:10.1002/ejoc.202301205
- Nobile, E.; Doche, F.; Castanheiro, T.; Musaev, D. G.; Besset, T. Copper-Catalyzed C-H (Phenylsulfonyl)difluoromethylation of Acrylamides: Scope, Mechanism, and Critical Role of Additives. Chemistry (Weinheim an der Bergstrasse, Germany) 2023, 30, e202303362. doi:10.1002/chem.202303362
- Doche, F.; Poisson, T.; Besset, T. Photocatalytic α-Trifluoromethylthiolation of N-Acyl Amines. ACS Catalysis 2023, 13, 14112–14120. doi:10.1021/acscatal.3c03249