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Construction of CF₂ moieties in FDA-approved drugs (2016–2025): industrial routes, mechanisms, and scale-up considerations

Wenyan Yao, Huanhuan Zhang, Xiaolong Yang and Feng Liu

Beilstein J. Org. Chem. 2026, 22, 1122–1150. https://doi.org/10.3762/bjoc.22.91

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Wenyan Yao, Huanhuan Zhang, Xiaolong Yang and Feng Liu

Beilstein J. Org. Chem. 2026, 22, 1122–1150. https://doi.org/10.3762/bjoc.22.91

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Yao, W.; Zhang, H.; Yang, X.; Liu, F. Beilstein J. Org. Chem. 2026, 22, 1122–1150. doi:10.3762/bjoc.22.91

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aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)

Construction of CF2 moieties in FDA-approved drugs (2016–2025): industrial routes, mechanisms, and scale-up considerations

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Construction of CF₂ moieties in FDA-approved drugs (2016–2025): industrial routes, mechanisms, and scale-up considerations