Kinetics and mechanism of vanadium catalysed asymmetric cyanohydrin synthesis in propylene carbonate

Michael North and Marta Omedes-Pujol

Beilstein J. Org. Chem. 2010, 6, 1043–1055. https://doi.org/10.3762/bjoc.6.119

Supporting Information

Chiral GC traces for all chiral cyanohydrin acetates and chiral HPLC data for methyl mandelate. NMR spectra of cyanohydrins in the presence of mandelic acid. Additionally, all of the kinetic data used to determine the catalyst order, the activation parameters and construct the Hammett plot are given.

Supporting Information File 1: Analytical data for all chiral compounds.
Format: PDF Size: 984.2 KB Download

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