A quantitative approach to nucleophilic organocatalysis

Herbert Mayr, Sami Lakhdar, Biplab Maji and Armin R. Ofial
Beilstein J. Org. Chem. 2012, 8, 1458–1478. https://doi.org/10.3762/bjoc.8.166

Cite the Following Article

A quantitative approach to nucleophilic organocatalysis
Herbert Mayr, Sami Lakhdar, Biplab Maji and Armin R. Ofial
Beilstein J. Org. Chem. 2012, 8, 1458–1478. https://doi.org/10.3762/bjoc.8.166

How to Cite

Mayr, H.; Lakhdar, S.; Maji, B.; Ofial, A. R. Beilstein J. Org. Chem. 2012, 8, 1458–1478. doi:10.3762/bjoc.8.166

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Silva Moratório de Moraes, R.; Tereza Miranda Martins, M.; Tavares de Almeida Pinto, G.; Couto Rodrigues, S.; Antunes do Nascimento, P.; Cardoso Cruz, C.; D'Oliveira Góes, K.; Claudia Cunha, A. An overview on generation and general properties of N-heterocyclic carbenes: Applications of 1,2,4-triazolium carbenes as metal free organocatalysts. Arabian Journal of Chemistry 2024, 17, 105527. doi:10.1016/j.arabjc.2023.105527
  • Hensinger, M. J.; Eitzinger, A.; Trapp, O.; Ofial, A. R. Nucleophilicity of 4-(Alkylthio)-3-imidazoline Derived Enamines. Chemistry (Weinheim an der Bergstrasse, Germany) 2023, 30, e202302764. doi:10.1002/chem.202302764
  • Eitzinger, A.; Reitz, J.; Antoni, P. W.; Mayr, H.; Ofial, A. R.; Hansmann, M. M. Mesoionische N‐Heterocyclische Olefine verschieben die obere Grenze der Nucleophilie‐Skala. Angewandte Chemie 2023, 135. doi:10.1002/ange.202309790
  • Eitzinger, A.; Reitz, J.; Antoni, P. W.; Mayr, H.; Ofial, A. R.; Hansmann, M. M. Pushing the Upper Limit of Nucleophilicity Scales by Mesoionic N-Heterocyclic Olefins. Angewandte Chemie (International ed. in English) 2023, 62, e202309790. doi:10.1002/anie.202309790
  • Nguyen, K.-U.; Zhang, Y.; Liu, Q.; Zhang, R.; Jin, X.; Taniguchi, M.; Miller, E. S.; Lindsey, J. S. Tolyporphins-Exotic Tetrapyrrole Pigments in a Cyanobacterium-A Review. Molecules (Basel, Switzerland) 2023, 28, 6132. doi:10.3390/molecules28166132
  • Nguyen Tran, A. T.; Wu, Z.; Chung, D. T. M.; Nalaoh, P.; Lindsey, J. S. Synthesis of model southern rim structures of photosynthetic tetrapyrroles and phyllobilins. New Journal of Chemistry 2023, 47, 13626–13637. doi:10.1039/d3nj02515b
  • Hensinger, M. J.; Closs, A. C.; Trapp, O.; Ofial, A. R. The effect of S-alkylation on organocatalytic enamine activation through imidazolidine-4-thiones. Chemical communications (Cambridge, England) 2023, 59, 8091–8094. doi:10.1039/d3cc01912h
  • Hayashi, Y.; Han, X.; Mori, N. Secondary Amine-Mediated Domino Reaction for the Synthesis of Substituted Quinolines from Dicyanoalkenes and Enynals. Chemistry (Weinheim an der Bergstrasse, Germany) 2023, 29, e202301093. doi:10.1002/chem.202301093
  • Nakano, Y.; Maddigan-Wyatt, J. T.; Lupton, D. W. Enantioselective Catalysis by the Umpolung of Conjugate Acceptors Involving N-Heterocyclic Carbene or Organophosphine 1,4-Addition. Accounts of chemical research 2023, 56, 1190–1203. doi:10.1021/acs.accounts.3c00063
  • Eitzinger, A.; Ofial, A. R. Reactivity of electrophilic cyclopropanes. Pure and applied chemistry. Chimie pure et appliquee 2023, 95, 389–400. doi:10.1515/pac-2023-0209
  • Chau Nguyen, K.; Nguyen Tran, A. T.; Wang, P.; Zhang, S.; Wu, Z.; Taniguchi, M.; Lindsey, J. S. Four Routes to 3-(3-Methoxy-1,3-dioxopropyl)pyrrole, a Core Motif of Rings C and E in Photosynthetic Tetrapyrroles. Molecules (Basel, Switzerland) 2023, 28, 1323. doi:10.3390/molecules28031323
  • Gallarati, S.; van Gerwen, P.; Laplaza, R.; Vela, S.; Fabrizio, A.; Corminboeuf, C. OSCAR: an extensive repository of chemically and functionally diverse organocatalysts. Chemical science 2022, 13, 13782–13794. doi:10.1039/d2sc04251g
  • Lakhdar, S. doi:10.1002/9783527832217.ch21
  • Reactivity Models in Organic Chemistry. Reactivity and Mechanism in Organic Chemistry; The Royal Society of Chemistry, 2022; pp 54–100. doi:10.1039/9781837670970-00054
  • Costa, A. M.; Castro‐Alvarez, A.; Fillot, D.; Vilarrasa, J. Computational Comparison of the Stability of Iminium Ions and Salts from Enals and Pyrrolidine Derivatives (Aminocatalysts). European Journal of Organic Chemistry 2022, 2022. doi:10.1002/ejoc.202200627
  • Corbisiero, D.; Fantoni, T.; Ferrazzano, L.; Martelli, G.; Cantelmi, P.; Mattellone, A.; Palladino, C.; Monari, M.; Pedrazzani, R.; Tolomelli, A.; Cabri, W. Fast MacMillan's Imidazolidinone-Catalyzed Enantioselective Synthesis of Polyfunctionalized 4-Isoxazoline Scaffolds. ACS omega 2022, 7, 26919–26927. doi:10.1021/acsomega.2c03477
  • Hayashi, Y. doi:10.1002/9781119736424.ch1
  • Proppe, J.; Kircher, J. Uncertainty Quantification of Reactivity Scales. Chemphyschem : a European journal of chemical physics and physical chemistry 2022, 23, e202200061. doi:10.1002/cphc.202200061
  • Mayr, H.; Hartnagel, M.; Ofial, A. R. Elucidation of the Nucleophilic Potential of Diazocyclopentadiene. Synthesis 2022, 55, 354–358. doi:10.1055/s-0041-1737327
  • Lei, C.-W.; Mu, B.-S.; Zhou, F.; Yu, J.-S.; Zhou, Y.; Zhou, J. Organocatalytic enantioselective reactions involving prochiral carbocationic intermediates. Chemical communications (Cambridge, England) 2021, 57, 9178–9191. doi:10.1039/d1cc03506a
Other Beilstein-Institut Open Science Activities