/ Home
/ SUBMISSION

/ The BJOC
/ Diamond Open Access
/ Journal Statistics
/ Editorial Board
/ Community
/ Call for papers

/ Latest Articles
/ Most accessed
/ Thematic issues
/ Volumes
/ Authors

/ E-Alerts

/ TWITTER
/ LINKEDIN
/ Mastodon
/ RSS FEED

Empty search

Article Type

Publication Date Range

Search Tips

This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.

Search Examples

aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)

BROWSE
Latest Articles
Most accessed
thematic issues
volumes
authors

BROWSE

Latest Articles Most Accessed Thematic Issues Volumes Authors

Author

Type 3 or more characters for results.

Type 2 or more characters for results.

Type 3 or more characters for results.

Type 2 or more characters for results.

1 article(s) from Akae, Yosuke

Cyclodextrin-based rotaxanes for polymer materials: challenge on simultaneous realization of inexpensive production and defined structures

Yosuke Akae

Beilstein J. Org. Chem. 2024, 20, 3026–3049, doi:10.3762/bjoc.20.252

PDF

Graphical Abstract

Figure 1: Overview of the CD-based rotaxane as a polymer material covered in this review.

Jump to Figure 1

Figure 2: CD structure.

Jump to Figure 2

Figure 3: Typical pathway for synthesizing CD-based rotaxanes.

Jump to Figure 3

Scheme 1: (A) Synthesis of α-CD-based [2]rotaxane via a metal–ligand complex. (B) Chemical structures of meth...

Jump to Scheme 1

Scheme 2: Synthesis of α-CD-based polyrotaxane.

Jump to Scheme 2

Scheme 3: Facile [3]rotaxane synthesis by the urea end-capping method.

Jump to Scheme 3

Figure 4: (A) Single-crystal structure of α-CD-based [3]rotaxane 3 and PMα-CD-based [3]rotaxane 4. (B) Schema...

Jump to Figure 4

Figure 5: Structural control of CD-based [2]rotaxane via (A) light irradiation and (B) light irradiation and ...

Jump to Figure 5

Figure 6: Relationship among the plus–minus signs of ICD, the position of the guest molecule, and the axis of...

Jump to Figure 6

Figure 7: Structural control of CD-based rotaxane via (A) redox reaction and (B) in a solvent.

Jump to Figure 7

Scheme 4: (A) Synthesis of pseudopolyrotaxane bearing an ABA triblock copolymer as an axle. (B) Two synthetic...

Jump to Scheme 4

Scheme 5: Slippage of size-complementary rotaxanes.

Jump to Scheme 5

Figure 8: (A) Reversible formation of the CD-based [2]rotaxane. (B) Deslipping reaction of the CD-based size-...

Jump to Figure 8

Figure 9: (A) Chemical structures of [3]rotaxanes 2 and 3. (B) Schematic of the deslipping reaction of [3]rot...

Jump to Figure 9

Figure 10: (A) Modification of the axle ends of [3]rotaxane by (1) bromination and (2) the Suzuki coupling rea...

Jump to Figure 10

Figure 11: (A) ICD spectra of [3]rotaxanes bearing acylated (top) and conventional (bottom) CDs. (B) Schematic...

Jump to Figure 11

Figure 12: Synthesis of macromolecular[3]rotaxane via a size-complementary protocol.

Jump to Figure 12

Figure 13: Conjugated polymer insulated by (A) β-CD. (B) Triphenylamine-substituted β-CD.

Jump to Figure 13

Figure 14: Synthesis of the VSC and successive rotaxane-crosslinked polymer (RCP) preparation.

Jump to Figure 14

Figure 15: (A) Chemical structure of the [3]rotaxane crosslinker (RC). (B) Schematic of the synthesis and de-c...

Jump to Figure 15

Figure 16: (A) Random vinylation of the CD-based [3]rotaxane; (B) Schematic of the reaction between α-CD and m...

Jump to Figure 16

Figure 17: (A) Aggregation of CD-based [3]rotaxane. (B) Schematic of the plausible mechanism of the aggregatio...

Jump to Figure 17

Album

Review

Published 19 Nov 2024

Full text

Other Beilstein-Institut Open Science Activities

/ Help / Support & Contact / E-Alerts / Privacy Policy / Terms & Conditions / Impressum