1 article(s) from Ando, Akane
Synthesis of alkynes from carbonyl compounds through one-carbon homologation.
Jump to Scheme 1
Reactions of magnesium alkylidene carbenoids 3, generated from sulfoxides 2 and iPrMgCl.
Jump to Scheme 2
Synthesis of sulfoxides 2 and 5–8 from carbonyl compounds 1.
Jump to Scheme 3
Reaction of sulfoxides 5 and 6 with isopropylmagnesium chloride.
Jump to Scheme 4
Reaction of sulfoxide 2c with isopropylmagnesium chloride.
Jump to Scheme 5
Reaction of 13C-labeled sulfoxides [13C]-(E)-2e and [13C]-(Z)-2e with iPrMgCl.
Jump to Scheme 6
A plausible reaction mechanism for the formation of alkynes 4. a) 1,2-Rearrangement readily takes p...
Jump to Scheme 7
Optimized geometries of reactant (E)-3e, transition state (E)-3e‡, and product 4e·MgCl2 for the FBW...
Jump to Figure 1
Beilstein J. Org. Chem. 2021, 17, 1352–1359, doi:10.3762/bjoc.17.94
Subscribe to our Latest Articles RSS Feed.
Register and get informed about new articles.
Follow the Beilstein-Institut