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Beilstein J. Org. Chem. 2025, 21, 1995–2006, doi:10.3762/bjoc.21.155
Graphical Abstract
Scheme 1: Illustration of chirality and the intrinsic remoteness of stereogenic elements for axial chirality ...
Scheme 2: Illustrations of assignment using point chirality.
Scheme 3: Examples of reactions that establish axial chirality derived from biaryls.
Scheme 4: Examples of reactions that establish axial chirality derived from C=C bonds.
Scheme 5: Examples of reactions that establish planar chirality.
Scheme 6: Examples of reactions that establish “inherent” chirality.
Scheme 7: Parameterization of asymmetric reactions that establish axial chirality.
Figure 1: The relationship between the numbers of non-hydrogen atoms (N) in the chiral catalysts and the valu...