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1 article(s) from Bochmann, Manfred

The trans-influence in gold chemistry from a catalytic perspective

Manfred Bochmann

Beilstein J. Org. Chem. 2026, 22, 838–856, doi:10.3762/bjoc.22.66

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Graphical Abstract

Scheme 1: Assessment of ligand influence by kinetic competition experiments.

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Scheme 2: Ligand types employed in the stabilisation of gold(III) complexes.

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Scheme 3: Au(III) π- and σ-complexes stabilised by C^N^C and C^N chelate ligands [28-32] and an example of a gold(II...

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Scheme 4: Gold(III) C^C chelate complexes.

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Figure 1: Examples of photoemissive gold(III) pyrazine complexes. Dr. J. Fernandez-Cestau is gratefully ackno...

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Scheme 5: Gold hydride complexes supported by tridentate pincer ligands and corresponding¹H NMR chemical shif...

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Scheme 6: Gold(III) hydride formation by oxygen transfer.

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Scheme 7: Heterolytic H–H bond cleavage by cationic Au(III) complexes [32,56].

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Scheme 8: Gold(III) models of the water-gas shift reaction [30].

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Scheme 9: Gold(III) hydride complexes supported by C^C and C^N chelate ligands [32,50].

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Scheme 10: O₂ insertions into Au–H bonds.

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Scheme 11: Alkyne, alkene and isocyanide hydroauration by a bimolecular gold radical mechanism [49,65,66].

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Scheme 12: Reactions of (C^C)Au–H with DMAD [50].

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Scheme 13: Alkyne hydroauration by a bimolecular Au(III)–Au(I)-assisted process [69].

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Scheme 14: Gold(III) π-allyl complexes.

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Scheme 15: Outer-sphere mechanism of ethylene insertion into Au–O bonds [20,84].

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Scheme 16: Catalytic acetylene functionalisation [86,87].

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Scheme 17: Examples of alkene insertions into Au–C bonds [88,89].

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Scheme 18: Examples of β-H elimination and chain walking processes in (C^P)-ligated gold alkyls [90].

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Scheme 19: Mechanism of alkyne hydroarylation with (C^P) gold catalysts [92].

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Scheme 20: Vinylic triflate esters by gold-catalysed nucleophilic attack on alkynes [94].

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Scheme 21: Gold-catalysed and gold-free steps in the formation of Heck-type olefins [97,99].

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Perspective

Published 01 Jun 2026

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