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1 article(s) from Cantín, Ángel

Diels–Alder reactions in confined spaces: the influence of catalyst structure and the nature of active sites for the retro-Diels–Alder reaction

Ángel Cantín,
M. Victoria Gomez and
Antonio de la Hoz

Beilstein J. Org. Chem. 2016, 12, 2181–2188, doi:10.3762/bjoc.12.208

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Scheme 1: Distribution of products in the Diels–Alder reaction between cyclopentadiene and p-benzoquinone.

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Figure 1: Conversion in the DAR catalysed by silica Beta zeolites and Aerosil.

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Figure 2: Effect of Lewis and Brønsted acid sites in the conversion (a) and selectivity (b) of the DAR.

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Figure 3: Effect of pore size in the conversion (a) and selectivity (b) of the DAR.

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Figure 4: Comparison of conversion (a) and selectivity (b) of the DAR catalysed by Al-Beta zeolite and MCM-41....

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Figure 5: Comparison of conversion (a) and selectivity (b) of the DAR catalysed extra-large pore 3D zeolites.

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Figure 6: Effect of the Si/Al ratio in the conversion (a) and selectivity (b) of the DAR.

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Figure 7: Effect of the reutilization of the catalysts in the conversion (a) and selectivity (b) of the DAR.

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Published 13 Oct 2016

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