2 article(s) from Cruickshank, Dyanne L
- Full Research Paper
- Published 29 Dec 2014
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Figure 1: Chemical structure of trans-resveratrol (1).
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Figure 2: DSC traces of RSV (a), TMA (b), TMA–RSV physical mixture (PM) (c), TMA–RSV preparation by kneading ...
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Figure 3: TG (red) and DSC (blue) traces for the hydrated TMA·RSV complex (top), and hot stage micrographs sh...
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Figure 4: The two symmetry-independent complex units of TMA·RSV·6.25H2O (A and B), with only the major compon...
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Figure 5: Representative atomic labelling for the ordered RSV molecule A (blue) present in host A and the two...
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Figure 6: Space-filling representations of the two independent complex units A (a) and B (b) of the complex T...
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Figure 7: Crystal packing for the complex TMA·RSV·6.25H2O projected down [010].
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Figure 8: The components of the disorder model for RSV in its inclusion complex with TMB (s.o.f. = 0.73 for t...
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Figure 9: The asymmetric unit in the crystal of TMB·RSV·5.6H2O (a), and the non-H atom and methylglucose ring...
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Figure 10: Space-filling model of the inclusion complex TMB·RSV·5.6H2O showing the inclusion of the RSV molecu...
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Figure 11: Packing arrangement in the crystal of TMB·RSV·5.6H2O viewed down [010] (a) and [100] (b). Hydrogen ...
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Figure 12: Structure of the host–guest complex DMB·RSV·4.0H2O (a), ring and atomic nomenclature for the host m...
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Figure 13: Space-filling model of the inclusion complex DMB·RSV·4.0H2O showing the encapsulation of part of th...
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Figure 14: Stereoview of two DMB·RSV·4.0H2O complex units related by a unit translation along the crystal a-ax...
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Figure 15: Projections of the crystal structure of the complex DMB·RSV·4H2O along [100] (a) and [010] (b). Hyd...
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Figure 16: Solubility of RSV as a function of [β-CD] (blue) and [γ-CD] (red) at 25 °C.
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Figure 17: Solubility of RSV as a function of the concentrations of TMB (light blue), DMB (red), HP-β-CD (gree...
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Supp. Info
- Full Research Paper
- Published 17 Jan 2013
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Graphical Abstract
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Figure 1: Chemical structure of fenitrothion (1).
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Figure 2: Representative TGA (top) and DSC (bottom) traces for DIMEB·1.
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Figure 3: The asymmetric unit in DIMEB•1 viewed along [010] (top) and [100] (bottom). H atoms are omitted for...
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Figure 4: The host molecules in the asymmetric unit of DIMEB·1 with the labelling of both residues and atoms ...
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Figure 5: The rotamers of 1 occupying the cavity of host molecule A. Common atoms have labels with suffix A, ...
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Figure 6: Stereoview of the three disordered guest components that occupy the cavity of host molecule B. Gues...
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Figure 7: Space-filling diagrams showing the relative orientations of guest molecules within the cavities of ...
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Figure 8: Packing diagrams of the DIMEB·1 structure, viewed along [100] (left) and [010] (right). The symmetr...
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Figure 9: Induced circular dichroism (a) and UV–vis (b) spectra of 1 in the presence of β-CD (10 mM, green), ...
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Scheme 1: Reaction of fenitrothion in basic media.
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Figure 10: Plot of kobs versus [DIMEB] for the hydrolysis reaction of fenitrothion with HO– at different conce...
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Scheme 2: Mechanism of the hydrolysis reaction of 1 mediated by DIMEB.
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