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1 article(s) from Das, Agnideep

Copper catalysis with redox-active ligands

Agnideep Das,
Yufeng Ren,
Cheriehan Hessin and
Marine Desage-El Murr

Beilstein J. Org. Chem. 2020, 16, 858–870, doi:10.3762/bjoc.16.77

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Scheme 1: Copper complexes with amidophenolate type benzoxazole ligands for alcohol oxidations.

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Scheme 2: Copper-catalyzed aerobic oxidation of alcohols and representative substrate scope.

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Scheme 3: Introduction of H-bonding network in the ligand coordination sphere.

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Scheme 4: Well-defined isatin copper complexes.

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Scheme 5: Catalyst control in the biomimetic phenol ortho-oxidation.

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Scheme 6: Structural diversity accessible by direct functionalization.

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Scheme 7: Copper-catalyzed trifluoromethylation of heteroaromatics with redox-active iminosemiquinone ligands....

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Scheme 8: Reversal of helical chirality upon redox stimuli and enantioselective Michael addition with a redox...

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Scheme 9: Interaction of guanidine-copper catalyst with oxygen and representative coupling products. ^a4 mol %...

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Scheme 10: Access to 1,2-oxy-aminoarenes by copper-catalyzed phenol–amine coupling.

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Scheme 11: Copper-catalyzed aziridination through molecular spin catalysis with redox-active iminosemiquinone ...

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Scheme 12: Nitrogen-group and carbon-group transfer in copper-catalyzed aziridination and cyclopropanation thr...

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Published 24 Apr 2020

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