1 article(s) from Fik, Christoph P
Top: Overview of the synthesized crosslinkers 1–6 and their correlation to each other via formal re...
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Synthetic pathways to structurally related compounds 1–6.
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Byproducts 8a and 9a.
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Synthetic pathways towards the planned cis-intermediate 19.
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Comparison of structural elements of 1–6 in the 1H NMR spectra (400 MHz).
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Refractive indices (RI) and viscosities (η) of crosslinkers 1–6 (* solid at room temperature).
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Exemplary photo-DSC plots for the curing of 1 and 3–6 at 37 °C.
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tmax for the curing of 1 and 3–6 at 37 °C (* no polymerization heat detected).
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Rp, max for the curing of 1–6 at 37 °C for a) top: ∆Hp of allyl groups = 87.5 kJ·mol−1 and b) botto...
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Polymerization heat, ∆Hp for the curing of 1–6 at 37 °C (* no polymerization heat detected).
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FTIR spectra of 1–6 before (top) and after (bottom) curing; the arrows indicate emerging, character...
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Proposed reaction pathways for the intramolecular propagation within 1.
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Flexural strength (FS) and E-modulus of cured crosslinkers 1–6; letters refer to statistical groups...
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Beilstein J. Org. Chem. 2017, 13, 372–383, doi:10.3762/bjoc.13.40
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