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Beilstein J. Org. Chem. 2026, 22, 828–837, doi:10.3762/bjoc.22.65
Graphical Abstract
Scheme 1: Synthesis of catechol-contained thioethers 1–7 and sulfoxides 1a–7a.
Figure 1: Molecular structures of 1a (a), 4a (b), 5a (c), 6a (d), 7a (e) (solvent molecules and fragment diso...
Figure 2: CV curves of 1 and 1a at the potential ranges: from −0.5 to 1.75 V for 1 (curve 1); from −0.5 to 1....
Scheme 2: Proposed mechanism of electrochemical transformations of catechol sulfoxides (path a – for 1a, 3a, ...
Figure 3: CV curve of 5a at the potential range from −0.50 to 1.40 V (curve 1); from −0.50 to 1.70 V (curve 2...
Figure 4: CV curves of electrolysis products of 7a at the potential ranges from 0.5 to −0.4 V (CH3CN, GC elec...
Scheme 3: Proposed mechanism of the reduction of electrogenerated o-benzoquinone.