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1 article(s) from Göker, Mustafa

The high potential of methyl laurate as a recyclable competitor to conventional toxic solvents in [3 + 2] cycloaddition reactions

Ayhan Yıldırım and
Mustafa Göker

Beilstein J. Org. Chem. 2025, 21, 2389–2415, doi:10.3762/bjoc.21.184

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Graphical Abstract

Figure 1: Versatile compounds via cycloaddition reactions.

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Scheme 1: Molecular structures of parent compounds 1a–f, 2a–d and cycloadducts 3a–u.

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Figure 2: a) Radar view of the physical properties of methyl laurate. b) Oral toxicity values of methyl laura...

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Figure 3: The oral toxicity values of all the solvents utilized in the present study obtained with ProTox 3.0....

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Figure 4: Ecological, environmental risk assessments, pesticide similarity and biodegradability assessments o...

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Figure 5: Ecological, environmental risk assessments, pesticide similarity and biodegradability assessments o...

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Figure 6: Ecological, environmental risk assessments, pesticide similarity and biodegradability assessments o...

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Figure 7: Various toxicity parameters of methyl laurate and a series of other solvents calculated by ADMETLab...

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Figure 8: a) Visualization of the localization of conventional organic and bio-based solvents in the Hansen s...

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Figure 9: Vapour pressures of the solvents used (values retrieved from the Chemeo molecular database).

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Scheme 2: Endo and exo stereoisomeric approaches of nitrone 1a and maleimide 2a in [3 + 2] cycloaddition reac...

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Figure 10: Signals of protons used in the calculation of the diastereomeric ratios (cis/trans) of cycloadditio...

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Figure 11: Results of studies on the recovery of solvents used in the reaction.

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Figure 12: Simplified scheme describing the reaction monitoring and solvent recovery.

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Figure 13: a) The superimposed spectra of C,N-diphenylnitrone and N-phenylmaleimide. b) The spectrum of methyl...

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Published 05 Nov 2025

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