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Beilstein J. Org. Chem. 2025, 21, 2447–2455, doi:10.3762/bjoc.21.186
Graphical Abstract
Figure 1: Representative examples of chiral selenium-containing compounds.
Scheme 1: Rhodium-catalyzed atroposelective C–H selenylation reported by You’s group [18].
Scheme 2: Rhodium-catalyzed atroposelective C–H selenylation reported by Li et al. [19].
Scheme 3: Organocatalytic asymmetric selenosulfonylation of alkynes.
Scheme 4: Rhodium-catalyzed asymmetric hydroselenation of 1-alkynylindoles. *DCE/DCM 2:1 (v/v), −50 °C.
Scheme 5: Organocatalytic atroposelective hydroselenation of alkynes. *Using cat.3, 4 h.