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Beilstein J. Org. Chem. 2014, 10, 2235–2242, doi:10.3762/bjoc.10.232
Graphical Abstract
Scheme 1: Principle of MOE with Ac4GlcNCyoc (1) and subsequent ligation by a DAinv reaction: The chemically m...
Figure 1: Hexosamine derivatives with cyclopropene tags. Cyoc = (2-methylcycloprop-2-en-1-yl)methoxycarbonyl,...
Scheme 2: Synthesis of the cyclopropene-modified hexosamine derivatives 1 and 2.
Scheme 3: Labeling strategy for metabolically incorporated monosaccharides.
Figure 2: Labeling of metabolically engineered cell-surface glycoconjugates. HEK 293T cells were grown for 48...
Figure 3: Western blot analysis of soluble glycoproteins. HeLa S3 cells were grown for 48 h with 100 µM cyclo...