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Beilstein J. Org. Chem. 2025, 21, 2542–2547, doi:10.3762/bjoc.21.196
Graphical Abstract
Figure 1: Selected natural uracil-containing nucleosides (the key perhydrofuropyran core highlighted in blue)....
Scheme 1: Synthetic strategies toward malayamycin A. (A) Previous synthetic route. (B) Our strategy toward th...
Scheme 2: Rational for intramolecular dipolar cycloaddition.
Scheme 3: Proposed pathway for the enone formation.
Scheme 4: Modified route to access the core of malayamycins.
Scheme 5: Attempting the Baeyer–Villiger reaction.
Beilstein J. Org. Chem. 2013, 9, 983–990, doi:10.3762/bjoc.9.113
Scheme 1: Biogenetic origin of Vinca alkaloids.
Scheme 2: Synthetic strategy for velbanamine based on chemoselective dioxygenation.
Scheme 3: Intramolecular oxyamidation of alkene 11 with phenyliodine(III)-bis(trifluoroacetate) (PIFA) by Tel...
Scheme 4: Copper-catalyzed amination of aryliodide.
Scheme 5: Revised PIFA-promoted cyclization of amide 11.
Scheme 6: PIFA-promoted cyclization to synthesize lactone.
Figure 1: Hydrolysis of iminolactone 18 under basic conditions.
Scheme 7: “Stop-and-flow” strategy for the stepwise dioxygenation of alkenes.
Scheme 8: “Stop-and-flow” strategy for the construction of γ-lactone derivatives.