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1 article(s) from Ievlev, Mikhail Yu.

Diastereoselective synthesis of 3,4-dihydro-2H-pyran-4-carboxamides through an unusual regiospecific quasi-hydrolysis of a cyano group

Mikhail Yu. Ievlev,
Oleg V. Ershov,
Mikhail Yu. Belikov,
Angelina G. Milovidova,
Viktor A. Tafeenko and
Oleg E. Nasakin

Full Research Paper
Published 27 Sep 2016

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1. Graphical Abstract
2. Scheme 1: An exclusive approach to 3,4-dihydro-2H-pyran-4-carboxamides from non-pyran sources.
  
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3. Scheme 2: Known approach to pyran derivatives based on ketonitriles 1.
  
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4. Figure 1: The molecular structure of 2a with atom-numbering scheme. Displacement ellipsoids are drawn at the ...
  
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5. Scheme 3: Plausible reaction pathways for 3,4-dihydro-2H-pyran-4-carbxamides 2 formation.
  
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Graphical Abstract

Beilstein J. Org. Chem. 2016, 12, 2093–2098, doi:10.3762/bjoc.12.198

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