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Beilstein J. Org. Chem. 2026, 22, 955–981, doi:10.3762/bjoc.22.75
Graphical Abstract
Figure 1: A design for electroorganic synthesis.
Figure 2: Modes of transition-metal-catalyzed electrochemical reduction of unsaturated C–C bonds.
Scheme 1: Electroreductive iron catalysis for alkyne semihydrogenation enabled by a cobaltocene redox mediato...
Scheme 2: Electrochemical reduction of unactivated alkenes via iron catalysis.
Scheme 3: Cobalt-catalyzed e-HAT for the reduction of alkynes.
Scheme 4: Dual cobalt catalyses for Z-selective semihydrogenation of alkynes.
Scheme 5: Electrochemical cobalt-catalyzed semideuteration of alkynes.
Scheme 6: Electrochemical cobalt catalysis for E-selective semihydrogenation of alkynes.
Scheme 7: Concerted proton–electron transfer-driven electrocatalytic reduction of alkenes.
Scheme 8: Electrochemical deuteration of alkenes via HAT using Co–H.
Scheme 9: Electrocatalytic reduction of alkynes by hydride transfer via PCET.
Scheme 10: Ni–H-free electrocatalytic semihydrogenation of alkynes by nickel catalysis.
Scheme 11: Ligand-based proton and electron transfer enabling electrocatalytic semihydrogenation of alkynes.
Scheme 12: Proton-modulated electrochemical Ni–H formation for the hydrogenation of alkynes.
Scheme 13: Nickel-catalyzed electrochemical semireduction of terminal alkynes.
Scheme 14: Full hydrogenation of alkynes via nickel hydride electrocatalysis.
Scheme 15: Ni–H-mediated electrochemical reduction of alkynes to alkanes.
Scheme 16: Electrochemical nickel-catalyzed hydrogenation of alkenes.
Scheme 17: Electrochemical Ni–H formation and hydrogenation of alkenes using a bifunctional ligand.
Scheme 18: Nickel hydride electrocatalysis for the hydrogenation of alkenes.