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1 article(s) from Juhaňáková, Eliška

Halogenated azobenzene acrylates: from efficient solution photoswitching to stable solid-state photochromic materials

Martina Vachtlová,
Michaela Fecková,
Vítězslav Zima,
Jan Podlesný,
Milan Klikar,
Oldřich Pytela,
Patrik Pařík,
Jakub Opršal,
Eliška Juhaňáková,
Veronika Chrtová and
Filip Bureš

Beilstein J. Org. Chem. 2026, 22, 782–794, doi:10.3762/bjoc.22.60

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Graphical Abstract

Figure 1: Molecular structure of investigated compounds 1a–f and known azobenzene derivatives A–C exploited i...

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Scheme 1: Synthesis of azobenzene-acrylate monomers 1a–f.

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Figure 2: Representative TGA (left) and DSC (right) curves of compounds 1c (black) and 1d (red).

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Figure 3: Energy level diagram of the electrochemically measured (black) and DFT-calculated (red for E-isomer...

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Figure 4: A) Experimentally measured UV–vis absorption spectra of the monosubstituted azobenzenes 1a, c and e...

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Figure 5: A) Experimentally measured UV–vis absorption spectra of the azobenzenes 1c and 1d at c = 4 × 10⁻⁵ M...

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Figure 6: A) HOMO/LUMO localizations in representative E-1a. B) HOMO−1/LUMO localizations in representative Z-...

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Figure 7: ¹H NMR spectra (500 MHz, CDCl₃, 20 °C) of azobenzene 1e corresponding to the dark-adapted PSS (blac...

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Figure 8: A) UV–vis absorption spectra of azobenzene 1e corresponding to the dark-adapted PSS (black), 355 nm...

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Figure 9: A) Thermal kinetics curve of compound 1e obtained by UV–vis monitoring at c = 4 × 10⁻⁵ M (DCE, 60 °...

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Figure 10: Photoswitching of target azobenzene 1a in the solid state (polymeric matrix). A) Polystyrene thin f...

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Published 21 May 2026

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