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Beilstein J. Org. Chem. 2026, 22, 131–142, doi:10.3762/bjoc.22.6
Graphical Abstract
Figure 1: Design of the functional dyes.
Scheme 1: Synthetic pathway of compounds.
Figure 2: Normalized absorption spectra of dyes 2a (a), 2b (b), and 2c (c); Photographs of dyes in the given ...
Figure 3: Absorption spectra of dyes 2a (a), 2b (b), and 2c (c) upon addition of 20 equiv of anions in DMSO; ...
Figure 4: Absorption spectra of titrated dyes (2a–c) with up to 50 equiv of CN− (a) 6:4, (b) 7:3, and (c) 4:6...
Figure 5: Partial 1H NMR spectral change of 2b (c = 10 mM) after up to 2 equiv of TBACN (c = 1 M) in DMSO-d6.
Scheme 2: Proposed interaction mechanism with CN−.
Figure 6: Optimized geometries of 2a–c and 2a–c+CN− obtained at the B3LYP/6-31+G(d,p) level.
Figure 7: Frontier molecular orbitals of a) 2a, b) 2a+CN−.
Figure 8: TGA curves of dyes.