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Beilstein J. Org. Chem. 2018, 14, 1859–1870, doi:10.3762/bjoc.14.160
Examples of reported SCS palladium(II) pincer complexes 1–13.
a) Reported SNS palladium(II) pincer complexes 14–16 as catalysts for Suzuki–Miyaura cross coupling ...
Synthesis of pincer ligands 19a–d and complexes 17a–d.
Molecular structure of 17d. Selected bond distances (Å) and bond angles (°); S(1)–Pd(1)–Cl(1) 93.27...
Proposed mechanism of the Suzuki–Miyaura coupling reaction using pincer complex 17d.
Energy profile for the oxidative addition reaction involving 4-bromoanisole and Pd(II) catalyst pre...
Investigation on the reusability of the catalyst.
Reusability of pincer complex 17d as a catalyst for the Suzuki–Miyaura cross coupling reaction.
Suzuki–Miyaura coupling reaction catalysed by the SN-bidentate complex 20a.
Beilstein J. Org. Chem. 2018, 14, 1668–1692, doi:10.3762/bjoc.14.143
Some sulfur-containing natural products.
Some natural products incorporating β-hydroxy sulfide moieties.
Some synthetic β-hydroxy sulfides of clinical value.
Alumina-mediated synthesis of β-hydroxy sulfides, ethers, amines and selenides from epoxides.
β-Hydroxy sulfide syntheses by ring opening of epoxides under different Lewis and Brønsted acid and...
n-Bu3P-catalyzed thiolysis of epoxides and aziridines to provide the corresponding β-hydroxy and β-...
Zinc(II) chloride-mediated thiolysis of epoxides.
Thiolysis of epoxides and one-pot oxidation to β-hydroxy sulfoxides under microwave irradiation.
Gallium triflate-catalyzed ring opening of epoxides and one-pot oxidation.
Thiolysis of epoxides and one-pot oxidation to β-hydroxy sulfoxides using Ga(OTf)3 as a catalyst.
Ring opening of epoxide using ionic liquids under solvent-free conditions.
N-Bromosuccinimide-catalyzed ring opening of epoxides.
LiNTf2-mediated epoxide opening by thiophenol.
Asymmetric ring-opening of cyclohexene oxide with various thiols catalyzed by zinc L-tartrate.
Catalytic asymmetric ring opening of symmetrical epoxides with t-BuSH catalyzed by (R)-GaLB (43) wi...
Asymmetric ring opening of meso-epoxides by p-xylenedithiol catalyzed by a (S,S)-(salen)Cr complex.
Desymmetrization of meso-epoxide with thiophenol derivatives.
Enantioselective ring-opening reaction of meso-epoxides with ArSH catalyzed by a C2-symmetric chira...
Enantioselective ring-opening reaction of stilbene oxides with ArSH catalyzed by a C2-symmetric chi...
Asymmetric desymmetrization of meso-epoxides using BINOL-based Brønsted acid catalysts.
Lithium-BINOL-phosphate-catalyzed desymmetrization of meso-epoxides with aromatic thiols.
Ring-opening reactions of cyclohexene oxide with thiols by using CPs 1-Eu and 2-Tb.
CBS-oxazaborolidine-catalyzed borane reduction of β-keto sulfides.
Preparation of β-hydroxy sulfides via connectivity.
Baker’s yeast-catalyzed reduction of sulfenylated β-ketoesters.
Sodium-mediated ring opening of epoxides.
Disulfide bond cleavage-epoxide opening assisted by tetrathiomolybdate.
Proposed reaction mechanism of disulfide bond cleavage-epoxide opening assisted by tetrathiomolybda...
Cyclodextrin-catalyzed difunctionalization of alkenes.
Zinc-catalyzed synthesis of β-hydroxy sulfides from disulfides and alkenes.
tert-Butyl hydroperoxide-catalyzed hydroxysulfurization of alkenes.
Proposed mechanism of the radical hydroxysulfurization.
Rongalite-mediated synthesis of β-hydroxy sulfides from styrenes and disulfides.
Proposed mechanism of Rongalite-mediated synthesis of β-hydroxy sulfides from styrenes and disulfid...
Copper(II)-catalyzed synthesis of β-hydroxy sulfides 15e,f from alkenes and basic disulfides.
CuI-catalyzed acetoxysulfenylation of alkenes.
CuI-catalyzed acetoxysulfenylation reaction mechanism.
One-pot oxidative 1,2-acetoxysulfenylation of Baylis–Hillman products.
Proposed mechanism for the oxidative 1,2-acetoxysulfination of Baylis–Hillman products.
1,2-Acetoxysulfenylation of alkenes using DIB/KI.
Proposed reaction mechanism of the diacetoxyiodobenzene (DIB) and KI-mediated 1,2-acetoxysulfenylat...
Catalytic asymmetric thiofunctionalization of unactivated alkenes.
Proposed catalytic cycle for asymmetric sulfenofunctionalization.
Synthesis of thiosugars using intramolecular thiol-ene reaction.
Synthesis of leukotriene C-1 by Corey et al.: (a) N-(trifluoroacetyl)glutathione dimethyl ester (3 ...
Synthesis of pteriatoxins with epoxide thiolysis to attain β-hydroxy sulfides. Reagents: (a) (1) K2...
Synthesis of peptides containing a β-hydroxy sulfide moiety.
Synthesis of diltiazem (12) using biocatalytic resolution of an epoxide followed by thiolysis.
Beilstein J. Org. Chem. 2015, 11, 583–588, doi:10.3762/bjoc.11.64
(i) CAN, wet silica, KBr, CH2Cl2/CH3CN (1:1), rt, 30 min; (ii) a. NaOAc, Ac2O, 140 °C, 3 h; b. K2CO3...
Single X-ray crystal structure of hemithioacetal 3a.
Proposed reaction sequence for the synthesis of a mixture of carbaldehydes 5a and 5a’ using Raney n...
K2CO3 (catalytic amount), MeOH, rt, 30 min.