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Beilstein J. Org. Chem. 2011, 7, 1577–1583, doi:10.3762/bjoc.7.186
Graphical Abstract
Scheme 1: Synthesis of functionalized phenols. Reagents and conditions: a) Boc2O, 1.0 equiv, THF, 0 °C → rt, ...
Scheme 2: Single substitution of hexachlorocyclotriphosphazene. Reagents and conditions: a) Cs2CO3, 1.67 equi...
Scheme 3: Synthesis of dansylated dendrons. Reagents and conditions: a) Cs2CO3, 11 equiv, THF, rt, 48 h. b) Cs...
Scheme 4: Synthesis of dabsylated dendrons. Reagents and conditions: a) Cs2CO3, 11 equiv, THF, rt, 48 h. b) T...
Figure 1: UV–vis spectra of compounds 8–10.
Figure 2: UV–vis spectra of compounds 4, 11 and 12 in dioxane.
Figure 3: Excitation (left) and emission (right) spectra of compounds 8–10 in 1,4-dioxane (the excitation spe...
Figure 4: Emission spectra (λexc = 347 nm) of compound 10 in mixtures water/dioxane with different molar frac...
Figure 5: λem,max of 10 in mixture water/dioxane vs molar fraction of water in dioxane (filled squares) and v...