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Beilstein J. Org. Chem. 2025, 21, 2243–2249, doi:10.3762/bjoc.21.171
Graphical Abstract
Figure 1: Representative natural products sharing the 3-methylpent-4-en-2-ol (MPO) moiety in their terminal s...
Scheme 1: (A) General strategy for the preparation of the fragment from an MPO-containing natural product. (B...
Scheme 2: Preparation of the C9–C12 fragment (7) from capsulactone (1).
Scheme 3: Synthesis of 4-methoxy-3-methyl-4-oxobutan-2-yl 4-nitrobenzoates (2S,3S)-8, (2S,3R)-9, (2R,3R)-10, ...
Figure 2: Extracted LC–MS chromatograms (m/z 304.1) of 4-methoxy-3-methyl-4-oxobutan-2-yl 4-nitrobenzoates. C...