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Beilstein J. Org. Chem. 2025, 21, 1924–1931, doi:10.3762/bjoc.21.150
Graphical Abstract
Figure 1: Envisaged connective synthesis of reactive probes 3 bearing S(VI) electrophilic warheads (WH). Dive...
Scheme 1: Synthesis of α-diazoamide substrates D1–5 of general structure 2 bearing S(VI) electrophiles. Panel...
Figure 2: Structures and reactions of co-substrates. Panel A: structures of the 16 selected co-substrates C1–...
Figure 3: Structures and structure elucidation of intermolecular reaction products. The relevant reactivity m...
Beilstein J. Org. Chem. 2013, 9, 775–785, doi:10.3762/bjoc.9.88
Scheme 1: Illustrative examples of a synthetic approach to natural-product-like molecules with over eighty mo...
Scheme 2: Overview of the proposed synthetic approach. FDIPES = diisopropyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10...
Figure 1: Structures of building blocks used in this study. Panel A: fluorous-tagged initiating building bloc...
Scheme 3: Synthesis of the initiating building blocks 6a and 6b. TBD = 1,5,7-triazabicyclo[4.4.0]dec-5-ene.
Scheme 4: Synthesis of the initiating building block 7.
Scheme 5: Fate of the metathesis reaction of the substrate 32.
Beilstein J. Org. Chem. 2005, 1, No. 2, doi:10.1186/1860-5397-1-2
Scheme 1:
Scheme 2:
Scheme 3:
Figure 1: Diastereoselective substitution of the N,O acetal 12
Scheme 4:
Figure 2: Diastereoselective Luche reduction of piperidinones
Scheme 5:
Figure 3: Diastereoselective dihydroxylation of unsaturated piperidines
Figure 4: Diagnostic nOe observations for the piperidine 22A
Figure 5: Diagnostic nOe observations for the piperidines 22C and 22D
Scheme 6:
Figure 6: Stereoselectivity of two-directional Luche reductions
Scheme 7:
Scheme 8:
Figure 7: Two-directional functionalisation by diastereoselective dihydroxylation