An overview on disulfide-catalyzed and -cocatalyzed photoreactions

Yeersen Patehebieke

Review
Published 23 Jun 2020

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1. Graphical Abstract
2. Scheme 1: [3 + 2] cyclization catalyzed by diaryl disulfide.
  
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3. Scheme 2: [3 + 2] cycloaddition catalyzed by disulfide.
  
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4. Scheme 3: Disulfide-bridged peptide-catalyzed enantioselective cycloaddition.
  
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5. Scheme 4: Disulfide-catalyzed [3 + 2] methylenecyclopentane annulations.
  
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6. Scheme 5: Disulfide as a HAT cocatalyst in the [4 + 2] cycloaddition reaction.
  
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7. Scheme 6: Proposed mechanism of the [4 + 2] cycloaddition reaction using disulfide as a HAT cocatalyst.
  
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8. Scheme 7: Disulfide-catalyzed ring expansion of vinyl spiro epoxides.
  
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9. Scheme 8: Disulfide-catalyzed aerobic oxidation of diarylacetylene.
  
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10. Scheme 9: Disulfide-catalyzed aerobic photooxidative cleavage of olefins.
  
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11. Scheme 10: Disulfide-catalyzed aerobic oxidation of 1,3-dicarbonyl compounds.
  
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12. Scheme 11: Proposed mechanism of the disulﬁde-catalyzed aerobic oxidation of 1,3-dicarbonyl compounds.
  
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13. Scheme 12: Disulfide-catalyzed oxidation of allyl alcohols.
  
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14. Scheme 13: Disulfide-catalyzed diboration of alkynes.
  
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15. Scheme 14: Dehalogenative radical cyclization catalyzed by disulfide.
  
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16. Scheme 15: Hydrodiﬂuoroacetamidation of alkenes catalyzed by disulfide.
  
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17. Scheme 16: Plausible mechanism of the hydrodiﬂuoroacetamidation of alkenes catalyzed by disulfide.
  
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18. Scheme 17: Disulfide-cocatalyzed anti-Markovnikov olefin hydration reactions.
  
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19. Scheme 18: Disulfide-catalyzed decarboxylation of carboxylic acids.
  
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20. Scheme 19: Proposed mechanism of the disulfide-catalyzed decarboxylation of carboxylic acids.
  
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21. Scheme 20: Disulfide-catalyzed decarboxylation of carboxylic acids.
  
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22. Scheme 21: Disulfide-catalyzed conversion of maleate esters to fumarates and 5H-furanones.
  
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23. Scheme 22: Disulfide-catalyzed isomerization of difluorotriethylsilylethylene.
  
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24. Scheme 23: Disulfide-catalyzed isomerization of allyl alcohols to carbonyl compounds.
  
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25. Scheme 24: Proposed mechanism for the disulfide-catalyzed isomerization of allyl alcohols to carbonyl compound...
  
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26. Scheme 25: Diphenyl disulfide-catalyzed enantioselective synthesis of ophirin B.
  
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27. Scheme 26: Disulfide-catalyzed isomerization in the total synthesis of (+)-hitachimycin.
  
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28. Scheme 27: Disulfide-catalyzed isomerization in the synthesis of (−)-gloeosporone.
  
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