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Beilstein J. Org. Chem. 2025, 21, 2456–2464, doi:10.3762/bjoc.21.187
Graphical Abstract
Figure 1: Isomerization of pyranoside and furanoside forms of unprotected ᴅ-galactose in an aqueous solution.
Figure 2: Known approaches for the stabilization of furanose forms (A)–(D).
Figure 3: Equilibrium between pyranose and furanose forms in benzoylated derivatives [26]. Conditions: TfOH (cat....
Figure 4: (A) Conformers arising during the rotation around the C5–C6 bond in pyranosides. (B) Furanoside rin...
Figure 5: Structures of conformers with minimum energy for the methyl β-ᴅ-galactoside (A) and its α-counterpa...
Figure 6: (A) Supposed PIF-rearrangement of monosaccharide 3. (B) Furanoside ring conformers of monosaccharid...
Figure 7: Graphical representations of the lowest energy conformers of phenyl β-ᴅ-galactosides 5 and 6.