1 article(s) from Rosair, Georgina M
Graphical Abstract
Scheme 1: Mild and direct C–H monofunctionalization of BQ 1: previous [14] and this work.
Figure 1: Benzoquinone derivatives synthesized for this study, with the donor in red and the benzoquinone acc...
Scheme 2: Synthesis of 2–4 via mild and direct C–H monofunctionalization of BQ (1).
Scheme 3: Synthesis of 5 via double Suzuki coupling.
Figure 2: Crystal structures of 3 and 4.
Figure 3: HOMO/LUMO and S1/T1 energies as well as HOMO/LUMO electron density distribution profiles of 2–5.
Figure 4: Cyclic voltammograms and differential pulse voltammograms of 2–5 in degassed DCM (scan rate = 100 m...
Figure 5: UV–vis absorption spectra of 2–5 in DCM and photoluminescence spectrum of 3 in degassed DCM and in ...
Figure 6: Time-resolved PL plots. a) Prompt decay and b) delayed decay curve of 3 in thin film (λexc = 378 nm...