1 article(s) from Rosair, Georgina M
- Full Research Paper
- Published 04 Dec 2019
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Graphical Abstract
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Scheme 1: Mild and direct C–H monofunctionalization of BQ 1: previous [14] and this work.
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Figure 1: Benzoquinone derivatives synthesized for this study, with the donor in red and the benzoquinone acc...
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Scheme 2: Synthesis of 2–4 via mild and direct C–H monofunctionalization of BQ (1).
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Scheme 3: Synthesis of 5 via double Suzuki coupling.
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Figure 2: Crystal structures of 3 and 4.
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Figure 3: HOMO/LUMO and S1/T1 energies as well as HOMO/LUMO electron density distribution profiles of 2–5.
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Figure 4: Cyclic voltammograms and differential pulse voltammograms of 2–5 in degassed DCM (scan rate = 100 m...
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Figure 5: UV–vis absorption spectra of 2–5 in DCM and photoluminescence spectrum of 3 in degassed DCM and in ...
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Figure 6: Time-resolved PL plots. a) Prompt decay and b) delayed decay curve of 3 in thin film (λexc = 378 nm...
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