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Beilstein J. Org. Chem. 2026, 22, 620–627, doi:10.3762/bjoc.22.48
Graphical Abstract
Figure 1: NHC–Cu complexes investigated in this study.
Scheme 1: Hypothetical mechanism for FA decomposition via decarboxylation of NHC–Cu–formato species.
Figure 2: Decomposition of FA catalyzed by NHC–Cu complexes in the presence of PhSiH3. Reaction conditions: f...
Figure 3: Decomposition of FA catalyzed by NHC–Cu complexes in the presence of different silanes. Reaction co...
Scheme 2: Isotopic labeling experiments.
Scheme 3: Proposed catalytic cycle for the NHC–Cu-catalyzed FA dehydrogenation.
Scheme 4: Dehydrogenative coupling of phenylsilane.