2 article(s) from Senge, Mathias O
- Full Research Paper
- Published 14 May 2021
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Figure 1: 5-Halo-substituted porphyrins.
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Figure 2: Expanded view (thermal ellipsoid) of compound 1 in the crystal showing (A) stacking, (B) tilted edg...
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Figure 3: Expanded view (ball and stick) of compound 2 in the crystal showing (A) stacking, (B) bromine atoms...
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Figure 4: Expanded view (ball and stick) of compound 3 in the crystal showing (A) stacking and (B) edge-on in...
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Figure 5: Hirshfeld surfaces of compounds 1–3.
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Figure 6: Contact percentages of compounds 1–3.
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Figure 7: NSD charts for compounds 1–3.
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Figure 8: Expanded view (thermal ellipsoid plot) of compound 2A showing (A) the edge-on and stacking interact...
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Figure 9: 5-Halo-15-phenyl-substituted porphyrins.
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Figure 10: Expanded view (thermal ellipsoid plot) of compound 4 showing (A) tilted alignment of porphyrin ring...
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Figure 11: Expanded view (thermal ellipsoid plot) of compound 5 showing (A) porphyrin stacking and (B) Br···H ...
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Figure 12: Expanded view (thermal ellipsoid plot) of compounds 6 (A and C) and 7 (B and D) showing (A) Br···H ...
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Figure 13: 5,15-Di-halo-substituted porphyrins.
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Figure 14: Expanded view (thermal ellipsoid plot) of compound 9 showing the Br···H interactions with (A) pyrro...
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Figure 15: Expanded view (thermal ellipsoid plot) of compound 10 showing the (A) Br···H interactions with toly...
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Figure 16: Expanded view (thermal ellipsoid plot) of compound 11 showing the (A) edge-on interactions, (B) edg...
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Figure 17: Expanded view (thermal ellipsoid plot) of compound 13 showing (A) Br···H interactions with pyrrole ...
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Figure 18: Expanded view (ball and stick) of compound 13A showing (A) Br···H interactions with pyrrole units a...
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Figure 19: 5,10-Di-halo-substituted porphyrins.
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Figure 20: Expanded view (ball and stick) of compound 16 showing (A) stacking, (B) head-to-tail alignment, (C)...
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Figure 21: Honorable mentions of halogen-substituted porphyrins taken from the CSD database.
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Figure 22: Series 1 – 5,15-di-halo-substituted porphyrins.
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Figure 23: Series 2 – increasing number of halogen substituents.
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Figure 24: Series 3 – 5,10-di-halo-substituted porphyrins.
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- Full Research Paper
- Published 17 Apr 2020
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Graphical Abstract
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Figure 1: Triptycene as a scaffold and selected porphyrin and BODIPY arrays.
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Scheme 1: Sonogashira cross-coupling reactions to form symmetric porphyrin and BODIPY triptycene-linked dyads....
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Scheme 2: Sonogashira cross-coupling reactions to form a triptycene-substituted porphyrin monomer and an unsy...
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Scheme 3: Synthesis of the triptycene-porphyrin-triptycene complex 18.
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Figure 2: Single crystal X-ray structure of triptycene 5. (a) Molecular structure of 5 in the crystal with hy...
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Figure 3: Single crystal X-ray structure of triptycene-linked zinc-nickel porphyrin dimer 16 showing the conf...
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Figure 4: Views of the single crystal X-ray structure of triptycene-linked zinc-nickel porphyrin dimer 16 sho...
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Figure 5: Expanded structure view of the triptycene-linked zinc-nickel porphyrin dimer 16 showing the repeati...
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Figure 6: UV–vis of symmetric and unsymmetric triptycene porphyrin dimers 9 and 16, and the triptycene porphy...
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Figure 7: Emission spectrum of symmetric and unsymmetric triptycene-linked porphyrin dimers 9 and 16, and a t...
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Figure 8: Compounds used for spectroscopic comparisons.
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Figure 9: UV–vis spectra of various porphyrin/BODIPY dimers with different linker groups in CHCl3.
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Figure 10: Fluorescence emission spectrum of various porphyrin/BODIPY dimers with different linker groups in C...
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