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1 article(s) from Sibi, Mukund P

Enantioselective radical chemistry: a bright future ahead

Anna C. Renner,
Sagar S. Thorat,
Hariharaputhiran Subramanian and
Mukund P. Sibi

Beilstein J. Org. Chem. 2025, 21, 2283–2296, doi:10.3762/bjoc.21.174

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Graphical Abstract

Figure 1: Methods of radical generation (A) and general types of radical reactions (B).

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Figure 2: Chiral catalysis in enantioselective radical chemistry [13-37].

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Scheme 1: Diastereo- and enantioselective additions of nucleophilic radicals to N-enoyloxazolidinone and pyrr...

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Scheme 2: Organocatalyzed formal [3 + 2] cycloadditions affording substituted pyrrolidines.

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Scheme 3: Synthesis of a hexacyclic compound via an organocatalyzed enantioselective polyene cyclization.

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Scheme 4: Nickel-catalyzed asymmetric cross-coupling reactions.

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Scheme 5: Chiral cobalt–porphyrin metalloradical-catalyzed radical cyclization reactions.

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Scheme 6: Enantioselective radical chaperone catalysis.

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Scheme 7: Enantioselective radical addition by decatungstate/iminium catalysis.

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Scheme 8: An ene-reductase-catalyzed photoenzymatic enantioselective radical cyclization/enantioselective HAT...

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Scheme 9: Photoenzymatic oxidative C(sp³)–C(sp³) coupling reactions between organoboron compounds and amino a...

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Scheme 10: Electrochemical α-alkenylation reactions of 2-acylimidazoles catalyzed by a chiral-at-rhodium Lewis...

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Scheme 11: Regio- and enantioselective electrochemical reactions of silyl polyenolates catalyzed by a chiral n...

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Published 28 Oct 2025

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