3 article(s) from Silvani, Alessandra
Graphical Abstract
Scheme 1: Reaction conducted according to the Ellman protocol.
Figure 1: Asymmetric unit of 2a, with the atom-numbering scheme. The crystallographic reference system is als...
Figure 2: Substrate scope of the borylcopper-mediated homocoupling of oxindole-based N-tert-butanesulfinyl im...
Scheme 2: Proposed mechanism for the borylcopper-mediated homocoupling of ketimines 1.
Graphical Abstract
Figure 1: Biologically active agents containing a 3-substituted-3-aminooxindole core.
Figure 2: ORTEP [37] view of one of the two independent molecules of 4a present in the asymmetric unit, showing t...
Figure 3: Proposed explanation of the stereochemical outcome of the Ugi 3CR.
Scheme 1: Post-Ugi transformation on compound 10a.
Scheme 2: Post-Ugi cyclization on compound 15a.
Graphical Abstract
Figure 1: THBC-DKP-based natural and synthetically made compounds.
Figure 2: THBC-DKP-based peptidomimetic 1a.
Figure 3: Geometric parameters for mimics 1a,b.
Figure 4: Perspective view of the low-energy conformers of 1a,b. Hydrogen atoms are omitted for clarity.
Scheme 1: Synthesis of the THBC-DKP-based peptidomimetic 1a.