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Beilstein J. Org. Chem. 2025, 21, 1924–1931, doi:10.3762/bjoc.21.150
Graphical Abstract
Figure 1: Envisaged connective synthesis of reactive probes 3 bearing S(VI) electrophilic warheads (WH). Dive...
Scheme 1: Synthesis of α-diazoamide substrates D1–5 of general structure 2 bearing S(VI) electrophiles. Panel...
Figure 2: Structures and reactions of co-substrates. Panel A: structures of the 16 selected co-substrates C1–...
Figure 3: Structures and structure elucidation of intermolecular reaction products. The relevant reactivity m...
Beilstein J. Org. Chem. 2025, 21, 1388–1396, doi:10.3762/bjoc.21.103
Figure 1: Structures of the pseudomonins D–G (1–4), pseudomonine (5), pseudomonin B (6) and salicylic acid (7...
Figure 2: Key HMBC, 1H-1H COSY and NOE correlations.
Figure 3: Extracted ion chromatogram and corresponding mass spectrum of compound 4 in the crude extract.
Figure 4: Proposed biosynthetic scheme for the formation of compounds (1–4).