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1 article(s) from Sun, Lingyu

Recent advances in the stereoselective synthesis of distal biaxially chiral molecules

Fanxing Zhou,
Chen Zhang,
Lingyu Sun,
Yiyun Fang,
Siming Zheng,
Lina Hu,
Mengyang Shen,
Zhen Zhao,
Wei Xu,
Yunqiang Sun and
Zi-Qiang Rong

Beilstein J. Org. Chem. 2026, 22, 461–479, doi:10.3762/bjoc.22.34

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Graphical Abstract

Figure 1: Natural products with various stereogenic axes.

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Scheme 1: Iridium complex-catalyzed asymmetrical synthesis of axially chiral (a) teraryl compounds 3 [40] and (b)...

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Scheme 2: Rhodium-catalyzed enantio- and diastereoselective cycloaddition of 1,2-bis(arylpropiolyl)benzenes w...

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Scheme 3: Synthesis of remote double axially chiral phosphoric acids.

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Scheme 4: Construction of chiral biaxial diphosphine ligand.

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Scheme 5: Atroposelective synthesis of biaxially chiral 1,4-distyryl-2,3-naphthalene diols.

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Scheme 6: H-Bond-enabled enantioselective synthesis of remote biaxially chiral amides mediated by the counter...

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Scheme 7: Enantioselective synthesis of biaryl products with twofold chiral axes.

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Scheme 8: Iridium-catalyzed C–H alkylation to obtain the distal biaxial atropisomers.

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Scheme 9: Co/SPDO-catalyzed biaxial bridged terphenyl compounds.

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Scheme 10: Atroposelective Co-catalyzed synthesis of pyridoindolones with two distinct C–N axes.

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Scheme 11: NHC organocatalytic synthesis of fused 1,4-biaxial uracils with C–C and C–N chiral axes.

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Scheme 12: Synthesis of the first biaxially chiral compound reported by Ito and co-workers [35].

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Scheme 13: Synthesis of chiral homoaryl compounds by Suzuki–Miyaura coupling.

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Scheme 14: Structurally complex APIs with multiple chiral axes.

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Scheme 15: Synthesis of helicenes containing stereogenic axes.

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Scheme 16: Chiral NHC–Pd complex-catalyzed Suzuki–Miyaura cross-coupling reaction for the synthesis of block-t...

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Scheme 17: Highly enantioselective C–H arylation of heteroarenes.

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Scheme 18: Synthesis of novel axially chiral N-arylcarbazole skeletons by the assembly of azidonaphthalenes an...

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Scheme 19: Catalytic enantioselective synthesis of axially chiral polycyclic aromatic hydrocarbons.

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Scheme 20: Catalytic synthesis of biaxial triphenylene block-transfer isomers.

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Scheme 21: A Pd(II)-catalyzed trans-selective C–H alkenylation strategy through thioether-directed olefination....

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Scheme 22: Synthesis of N-arylphthalimides from prochiral maleimides and NHC-activated dienolides.

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Scheme 23: Ni-catalyzed synthesis of triaxially chiral polysubstituted naphthalene scaffolds.

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Scheme 24: Enantioselective Ni-catalyzed Suzuki–Miyaura cross-coupling reaction.

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Scheme 25: The stereoselective synthesis of axial chiral indole–quinoline systems.

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Scheme 26: The synthesis of bisbenzofuran atropisomeric oligoarenes containing two distal C–C stereogenic axes....

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Review

Published 16 Mar 2026

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