1 article(s) from Veit, Philipp
Graphical Abstract
Scheme 1: Imine formation and isomerization reactions from NH carbene complexes Cr(CO)5(E-2) (a) [27], Cr(CO)5(E/Z...
Scheme 2: Synthesis of W(CO)5(E-2) from W(CO)5(1Et) [20,21] and aminoferrocene [40,41] with concomitant formation of E-1,2-...
Scheme 3: Reaction pathways 1a/1b (migration–elimination) and 2a/2b (elimination–migration) for the formation...
Scheme 4: Reaction pathways 3a/3b/3c (CO dissociation) for the formation of imine E-3 from W(CO)5(E-2).
Figure 1: DFT calculated oxidative addition/pseudorotation/reductive elimination pathway 3c from W(CO)4(E-2) ...
Figure 2: DFT calculated geometries of the two hydrido intermediates cis(N,H)-W(CO)4(H)(Z-15) and cis(C,H)-W(...
Scheme 5: Proposed reaction sequence from W(CO)5(E-2) to W(CO)5(PPh3) in the presence of triphenylphosphane.