1 article(s) from Veit, Philipp
- Full Research Paper
- Published 27 Jun 2016
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Graphical Abstract
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Scheme 1: Imine formation and isomerization reactions from NH carbene complexes Cr(CO)5(E-2) (a) [27], Cr(CO)5(E/Z...
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Scheme 2: Synthesis of W(CO)5(E-2) from W(CO)5(1Et) [20,21] and aminoferrocene [40,41] with concomitant formation of E-1,2-...
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Scheme 3: Reaction pathways 1a/1b (migration–elimination) and 2a/2b (elimination–migration) for the formation...
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Scheme 4: Reaction pathways 3a/3b/3c (CO dissociation) for the formation of imine E-3 from W(CO)5(E-2).
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Figure 1: DFT calculated oxidative addition/pseudorotation/reductive elimination pathway 3c from W(CO)4(E-2) ...
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Figure 2: DFT calculated geometries of the two hydrido intermediates cis(N,H)-W(CO)4(H)(Z-15) and cis(C,H)-W(...
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Scheme 5: Proposed reaction sequence from W(CO)5(E-2) to W(CO)5(PPh3) in the presence of triphenylphosphane.
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