2 article(s) from Vors, Jean-Pierre
Pd-catalyzed monofluoromethylation of pinacol phenylboronate .
Jump to Scheme 1
Cu-catalyzed monofluoromethylation with 2-PySO2CHFCOR followed by desulfonylation .
Jump to Scheme 2
Cu-catalyzed difluoromethylation with α-silyldifluoroacetates .
Jump to Scheme 3
Mechanism of the Cu-catalyzed C–CHF2 bond formation of α,β-unsaturated carboxylic acids through dec...
Jump to Figure 1
Fe-catalyzed decarboxylative difluoromethylation of cinnamic acids .
Jump to Scheme 4
Preliminary experiments for investigation of the mechanism of the C–H trifluoromethylation of N-ary...
Jump to Scheme 5
Plausible catalytic cycle proposed by Z.-J. Shi et al. for the trifluoromethylation of acetanilides ...
Jump to Figure 2
Plausible catalytic cycle proposed by M. S. Sanford et al. for the perfluoroalkylation of simple ar...
Jump to Figure 3
Postulated reaction pathway for the Ag/Cu-catalyzed trifluoromethylation of aryl iodides by Z. Q. W...
Jump to Figure 4
Postulated reaction mechanism for Cu-catalyzed trifluoromethylation reaction using MTFA as trifluor...
Jump to Figure 5
Formal Heck-type trifluoromethylation of vinyl(het)arenes by M. Sodeoka et al. .
Jump to Scheme 6
Proposed catalytic cycle for the copper-catalyzed trifluoromethylation of (het)arenes in presence o...
Jump to Figure 6
Proposed catalytic cycle for the copper-catalyzed trifluoromethylation of N,N-disubstituted (hetero...
Jump to Figure 7
Proposed catalytic cycle by Y. Zhang and J. Wang et al. for the copper-catalyzed trifluoromethylati...
Jump to Figure 8
Mechanistic rationale for the trifluoromethylation of arenes in presence of Langlois’s reagent and ...
Jump to Figure 9
Trifluoromethylation of 4-acetylpyridine with Langlois’s reagent by P. S. Baran et al. (* Stirring ...
Jump to Scheme 7
Catalytic copper-facilitated perfluorobutylation of benzene with C4F9I and benzoyl peroxide .
Jump to Scheme 8
F.-L. Qing et al.’s proposed mechanism for the copper-catalyzed trifluoromethylation of (hetero)are...
Jump to Figure 10
Mechanism of the Cu-catalyzed/Ru-photocatalyzed trifluoromethylation and perfluoroalkylation of ary...
Jump to Figure 11
Proposed mechanism for the Cu-catalyzed trifluoromethylation of aryl- and vinyl boronic acids with ...
Jump to Figure 12
Possible mechanism for the Cu-catalyzed decarboxylative trifluoromethylation of cinnamic acids .
Jump to Figure 13
Ruthenium-catalyzed perfluoroalkylation of alkenes and (hetero)arenes with perfluoroalkylsulfonyl c...
Jump to Scheme 9
N. Kamigata et al.’s proposed mechanism for the Ru-catalyzed perfluoroalkylation of alkenes and (he...
Jump to Figure 14
Proposed mechanism for the Ru-catalyzed photoredox trifluoromethylation of (hetero)arenes with trif...
Jump to Figure 15
Late-stage trifluoromethylation of pharmaceutically relevant molecules with trifluoromethanesulfony...
Jump to Figure 16
Proposed mechanism for the trifluoromethylation of alkenes with trifluoromethyl iodide under Ru-bas...
Jump to Figure 17
Formal perfluoroakylation of terminal alkenes by Ru-catalyzed cross-metathesis with perfluoroalkyle...
Jump to Scheme 10
One-pot Ir-catalyzed borylation/Cu-catalyzed trifluoromethylation of complex small molecules by Q. ...
Jump to Figure 18
Mechanistic proposal for the Ni-catalyzed perfluoroalkylation of arenes and heteroarenes with perfl...
Jump to Figure 19
Electrochemical Ni-catalyzed perfluoroalkylation of 2-phenylpyridine (Y. H. Budnikova et al.) .
Jump to Scheme 11
Fe(II)-catalyzed trifluoromethylation of arenes and heteroarenes with trifluoromethyl iodide (T. Ya...
Jump to Scheme 12
Mechanistic proposal by T. Yamakawa et al. for the Fe(II)-catalyzed trifluoromethylation of arenes ...
Jump to Figure 20
Ytterbium-catalyzed perfluoroalkylation of dihydropyran with perfluoroalkyl iodide (Y. Ding et al.) ...
Jump to Scheme 13
Mechanistic proposal by A. Togni et al. for the rhenium-catalyzed trifluoromethylation of arenes an...
Jump to Figure 21
Mechanism of the Cu-catalyzed oxidative trifluoromethylthiolation of arylboronic acids with TMSCF3 ...
Jump to Figure 22
Removal of the 8-aminoquinoline auxiliary .
Jump to Scheme 14
Mechanism of the Cu-catalyzed trifluoromethylthiolation of C–H bonds with a trifluoromethanesulfony...
Jump to Figure 23
Beilstein J. Org. Chem. 2013, 9, 2476–2536, doi:10.3762/bjoc.9.287
Preparation of trifluoromethyl ethers via a chlorination/fluorination sequence.
Preparation of trifluoromethyl ethers via an in situ chlorination/fluorination sequence.
Preparation of trifluoromethyl ethers via chlorothionoformates.
Preparation of trifluoromethyl ethers via fluoroformates.
Oxidative desulfurization-fluorination toward trifluoromethyl ethers.
Mechanism of the oxidative desulfurization-fluorination.
Umemoto's O-(trifluoromethyl)dibenzofuranium salts 4 as CF3-transfer agents.
Togni's approach using hypervalent iodine compounds as CF3-transfer agents.
TAS OCF3 as a nucleophilic OCF3-transfer agent.
Mesomeric structures of the OCF3-group.
Structures of 6 and 7.
Conformational preference of the trifluoromethoxy group on aryl rings.
Nitration of trifluoromethoxy benzene.
Synthesis and Nitration of N-Acetyl-(trifluoromethoxy)anilines.
Bromine/lithium exchange of bromo(trifluoromethoxy)benzenes.
Metalation of (trifluoromethoxy)benzene.
Metalation of (trifluoromethoxy)naphthalenes.
Competition between -CF3- and -OCF3 in Metalation reactions.
Jump to Scheme 15
Competition between -F- and -OCF3 in Metalation reactions.
Jump to Scheme 16
Metalation of trifluoromethoxyanisoles.
Jump to Scheme 17
Direction of π-polarization depending on the substituent as described by Schlosser et al. .
Metalation of Bromo(trifluoromethoxy)benzenes.
Jump to Scheme 18
Aryne formation from bromo(trifluoromethoxy)phenyllithiums and subsequent Diels-Alder cycloaddition...
Jump to Scheme 19
Metalation of (trifluoromethoxy)anilines.
Jump to Scheme 20
Beilstein J. Org. Chem. 2008, 4, No. 13, doi:10.3762/bjoc.4.13
Subscribe to our Latest Articles RSS Feed.
Register and get informed about new articles.
Follow the Beilstein-Institut